Synthesis, Structure and Surface Photovoltage Characterization of [Co(en)3]2(Zr2F12) (ZrF6H2O) • H2O

被引：1

作者：

Han Yi-De ^{[1
]}

Du Yu ^{[2
]}

Li Yi ^{[1
]}

Song Xiao-Wei ^{[1
]}

Yu Ji-Hong ^{[1
]}

Xu Ru-Ren ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Jilin Univ, Coll Elect Sci & Engn, Changchun 130012, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2012年 / 33卷 / 05期

关键词：

Zirconium fluoride; Cobalt ammine complex; Hydrogen-bonding; Photovoltage; SENSITIZED SOLAR-CELLS; CRYSTAL-STRUCTURES; CHANNEL STRUCTURE; SPECTROSCOPY; COMPLEXES; MOBILITY;

D O I：

10.3969/j.issn.0251-0790.2012.05.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Co(en)(3)](2)(Zr2F12) (ZrF6H2O) center dot H2O(1) was prepared successfully at room temperature and structurally characterized by single-crystal X-ray diffraction analysis. Crystal data for compound 1 are as follows: monoclinic, C2/c, a = 3. 06110 (17) nm, b = 0. 877680 (5) nm, c = 1. 50811 (9) nm, beta 118. 897 degrees, V = 3. 547 (4) nm(3), Z = 8. Compound 1 consists of one binuclear [Zr2F12](4-)unit, one mono-nuclear [ZrF6H2O](2-)unit, one cobalt ammine complex [Co(en)(3)](3+) unit and one water molecule, among which exist extensive hydrogen bonds. The surface photovoltage spectrum of compound 1 exhibit a signal at 339 nm, which is attributed to the cooperative behaviors between cobalt ammine complex and metal fluoride ions through interactions of them.

引用

页码：876 / 879

页数：4

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