Modeling of complex-forming chromatographic systems under ionizing radiation conditions

被引：1

作者：

Kharitonov, O. V. ^{[1
]}

Firsova, L. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 117071, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2011年 / 85卷 / 06期

关键词：

complex-forming chromatography; eluent; complexone; radiolysis; RARE-EARTH ELEMENTS; HIGH ABSORBED DOSAGES; SEPARATION;

D O I：

10.1134/S0036024411060161

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Simulation of displacement complex-forming chromatography systems under irradiation conditions was performed for eluents based on diethylenetriaminepentaacetate. Acetates, iminodiacetates, formates, glycinates, and succinates were considered as radiolysis products. The model with an acetic acid salt as the radiolysis product best correlated with the experimental data.

引用

页码：1054 / 1060

页数：7

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