Hydrogenation of 2-butyne-1,4-diol to butane-1,4-diol in supercritical carbon dioxide

被引：13
|
作者：
Zhao, FY
Ikushima, Y
Arai, M
机构：
[1] Natl Inst Adv Ind Sci & Technol, Supercrit Fluid Res Ctr, Sendai, Miyagi 9838551, Japan
[2] Japan Sci & Technol Corp, CREST, Tokyo, Japan
[3] Hokkaido Univ, Grad Sch Engn, Div Engn & Mat Sci, Sapporo, Hokkaido 0608628, Japan
来源：
GREEN CHEMISTRY | 2003年 / 5卷 / 05期
关键词：
D O I：
10.1039/b306560j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrogenation of 2-butyne-1,4-diol to butane-1,4-diol has been successfully conducted in supercritical carbon dioxide at 323 K with a high selectivity of 84% for butane-1,4-diol at 100% conversion. No catalysts are needed since the reaction is promoted by the stainless steel reactor wall.
引用
收藏
页码：656 / 658
页数：3
相关论文
共 50 条
  • [1] 2-butyne-1,4-diol
    Steiner, T
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 (52) : 2885 - 2887
  • [2] Continuous hydrogenation of 2-butyne-1,4-diol to 2-butene- and butane-1,4-diols
    Rode, CV
    Tayade, PR
    Nadgeri, JM
    Jaganathan, R
    Chaudhari, RV
    ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2006, 10 (02) : 278 - 284
  • [3] ANALYSIS OF 2-BUTYNE-1,4-DIOL HYDROGENATION PRODUCTS
    KOZLOVA, LM
    LITVIN, EF
    IZVESTIYA AKADEMII NAUK SSSR-SERIYA KHIMICHESKAYA, 1970, (04): : 942 - +
  • [4] Platinum catalyzed hydrogenation of 2-butyne-1,4-diol
    Telkar, MM
    Rode, CV
    Jaganathan, R
    Rane, VH
    Chaudhari, RV
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 187 (01) : 81 - 93
  • [5] Hydrogenation of 2-butyne-1,4-diol in supercritical carbon dioxide promoted by stainless steel reactor wall
    Zhao, FY
    Ikushima, Y
    Arai, M
    CATALYSIS TODAY, 2004, 93-5 : 439 - 443
  • [6] SOME REACTIONS OF 2-BUTYNE-1,4-DIOL
    HENNION, GF
    KUPIECKI, FP
    JOURNAL OF ORGANIC CHEMISTRY, 1953, 18 (11): : 1601 - 1609
  • [7] ZINC ELECTROWINNING WITH 2-BUTYNE-1,4-DIOL
    PIRON, DL
    MATHIEU, D
    DAMBOISE, M
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1987, 65 (04): : 685 - 688
  • [8] Catalytic hydrogenation of 2-butyne-1,4-diol to 2-butene-1,4-diol at atmospheric pressure in the liquid phase
    Pyatnitsyna, EV
    El'chaninov, MM
    Savost'yanov, AP
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2006, 79 (01) : 89 - 92
  • [9] Catalytic hydrogenation of 2-butyne-1,4-diol to 2-butene-1,4-diol at atmospheric pressure in the liquid phase
    E. V. Pyatnitsyna
    M. M. El’chaninov
    A. P. Savost’yanov
    Russian Journal of Applied Chemistry, 2006, 79 : 89 - 92
  • [10] A CHEMICAL STUDY OF 2-BUTYNE-1,4-DIOL
    DAMBOISE, M
    MATHIEU, D
    PIRON, DL
    TALANTA, 1988, 35 (10) : 763 - 768
12345