Mesoscale organization of flower-like La2O2CO3 and La2O3Microspheres

被引:35
作者
Sun, Chunwen [1 ]
Xiao, Guoliang [1 ]
Li, Hong [1 ]
Chen, Liquan [1 ]
机构
[1] Chinese Acad Sci, Inst Phys, Nanoscale Phys & Devices Lab, Beijing 100080, Peoples R China
关键词
D O I
10.1111/j.1551-2916.2007.01756.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Well-dispersed spherical lanthanum oxycarbonate (La2O2CO3) and La2O3 particles with a flower-like morphology were synthesized via a simultaneous polymerization-precipitate reaction, metamorphic reconstruction, and mineralization under a hydrothermal condition as well as subsequent calcination. The La2O2CO3 and La2O3 microspheres obtained consist of about 20 or 40 nm thick nanosheets as petals, respectively. They have an open three-dimensional mesoporous and hollow structure and possess a high surface area, large pore volume, and marked thermal stability. These novel porous structural lanthanum-based materials could be used as catalyst supports for many reactions.
引用
收藏
页码:2576 / 2581
页数:6
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