共 34 条
Mesoscale organization of flower-like La2O2CO3 and La2O3Microspheres
被引:35
作者:
Sun, Chunwen
[1
]
Xiao, Guoliang
[1
]
Li, Hong
[1
]
Chen, Liquan
[1
]
机构:
[1] Chinese Acad Sci, Inst Phys, Nanoscale Phys & Devices Lab, Beijing 100080, Peoples R China
关键词:
D O I:
10.1111/j.1551-2916.2007.01756.x
中图分类号:
TQ174 [陶瓷工业];
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
Well-dispersed spherical lanthanum oxycarbonate (La2O2CO3) and La2O3 particles with a flower-like morphology were synthesized via a simultaneous polymerization-precipitate reaction, metamorphic reconstruction, and mineralization under a hydrothermal condition as well as subsequent calcination. The La2O2CO3 and La2O3 microspheres obtained consist of about 20 or 40 nm thick nanosheets as petals, respectively. They have an open three-dimensional mesoporous and hollow structure and possess a high surface area, large pore volume, and marked thermal stability. These novel porous structural lanthanum-based materials could be used as catalyst supports for many reactions.
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页码:2576 / 2581
页数:6
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