Synthesis and characterization of a new class of heteronuclear derivatives of zirconium(IV)

被引:6
作者
Sharma, NB [1 ]
Singh, A [1 ]
Mehrotra, RC [1 ]
机构
[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India
关键词
D O I
10.1007/s11243-004-3767-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reactions of Zr{Al(OPri)(4)}(2)Cl-2 or Zr{Nb(OPri)(6)}(2)Cl-2 with KNb(OPri)(6)/ KAl(OPri)(4) and diethanolamines RN(CH2CH2OH)(2) [ R = H( L-H H-2), Me( L-Me H-2), and Ph(L-Ph H-2)] in the presence of two equivalents of Et3N yield interesting hetero(bi- and tri-) nuclear derivatives (1) -( 8). All of these new derivatives have been characterized by elemental analyses, molecular weight measurements, and spectroscopic studies.
引用
收藏
页码:103 / 106
页数:4
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