Effect of glass transition on the concentration dependence of self-diffusion coefficients

被引：4

作者：

Vrentas, JS ^{[1
]}

Vrentas, CM ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2003年 / 89卷 / 06期

关键词：

glass transition; diffusion; solution properties;

D O I：

10.1002/app.12349

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The free-volume theory of diffusion is used to predict the effect of the glass transition on the concentration dependence of the solvent self-diffusion coefficient at constant temperature. The theoretical prediction is in agreement with experimental data. (C) 2003 Wiley Periodicals, Inc.

引用

页码：1682 / 1684

页数：3

共 50 条

[1] Effect of glass transition on the concentration dependence of self-diffusion coefficients
Vrentas, J.S. (jsv1@psu.edu), 1682, John Wiley and Sons Inc. (89):
[2] CONCENTRATION-DEPENDENCE OF POLYMER SELF-DIFFUSION COEFFICIENTS
VRENTAS, JS
DUDA, JL
NI, LW
MACROMOLECULES, 1983, 16 (02) : 261 - 266
[3] CONCENTRATION-DEPENDENCE OF SOLVENT SELF-DIFFUSION COEFFICIENTS
VRENTAS, JS
CHU, CH
JOURNAL OF APPLIED POLYMER SCIENCE, 1987, 34 (02) : 587 - 592
[4] CONCENTRATION-DEPENDENCE OF SELF-DIFFUSION COEFFICIENTS OF WATER IN ELECTROLYTE SOLUTIONS
SAZONOV, AM
OLEVSKII, VM
PORAIKOS.AB
SKOBELEV, VN
SHMUILOV.GA
ZHURNAL STRUKTURNOI KHIMII, 1973, 14 (06): : 968 - 972
[5] HIGHER TERMS IN CONCENTRATION-DEPENDENCE OF SELF-DIFFUSION COEFFICIENTS IN ELECTROLYTES
TURQ, P
CHEMICAL PHYSICS LETTERS, 1972, 15 (04) : 579 - &
[6] Generalized concentration dependence of globular protein self-diffusion coefficients in aqueous solutions
Nesmelova, IV
Skirda, VD
Fedotov, VD
BIOPOLYMERS, 2002, 63 (02) : 132 - 140
[7] Generalized concentration dependence of self-diffusion coefficients in poly(allylcarbosilane) dendrimer solutions
Sagidullin, AI
Muzafarov, AM
Krykin, MA
Ozerin, AN
Skirda, VD
Ignat'eva, GM
MACROMOLECULES, 2002, 35 (25) : 9472 - 9479
[8] CONCENTRATION-DEPENDENCE OF THE SELF-DIFFUSION COEFFICIENT
MARQUSEE, JA
DEUTCH, JM
JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (10): : 5396 - 5397
[9] THE CONCENTRATION DEPENDENCE OF THE SELF-DIFFUSION COEFFICIENTS OF STRONTIUM ION IN AQUEOUS POLYSTYRENESULFONIC ACID SOLUTIONS
HARDY, EP
STEIGMAN, J
JOURNAL OF POLYMER SCIENCE, 1960, 44 (144): : 475 - 482
[10] EFFECT OF IONS ON SELF-DIFFUSION OF WATER .I. CONCENTRATION DEPENDENCE
MCCALL, DW
DOUGLASS, DC
JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (06): : 2001 - &

← 1 2 3 4 5 →