Anionic ring-opening polymerization of cyclic organosiloxanes using phosphorus ylides as strong non-ionic bases

被引：7
作者：
Bessmertnykh, A
Ben, F
Baceiredo, A
Mignani, G
机构：
[1] Rhodia Rech, F-69192 St Fons, France
[2] Univ Toulouse 3, UMR 5069, Lab Heterochim Fondamentale & Appl, F-31062 Toulouse 04, France
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 686卷 / 1-2期
关键词：
phosphorus ylides; non-ionic bases; polymerization; octamethylcyclotetrasiloxane;
D O I：
10.1016/S0022-328X(03)00617-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Phosphonium alcoholates obtained by treatment of dimethylmethylene-[tris(dimethylamino)]phosphorane (1) with an excess of alcohol polymerize cyclic siloxanes (134) at room temperature. The thermal lability of this system permits simplifies polymer purification. (C) 2003 Elsevier B.V. All rights reserved.
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收藏
页码：281 / 285
页数：5
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