X-ray nanospectroscopy for attogram-scale two-dimensional nanomaterials using photoelectron emission microscopy

被引:1
作者
Kotani, Y. [1 ,5 ]
Taniuchi, T. [2 ]
Osada, M. [3 ]
Sasaki, T. [3 ]
Kotsugi, M. [4 ]
Ohkochi, T. [4 ]
Watanabe, Y. [4 ]
Ono, K. [1 ,5 ]
机构
[1] High Energy Accelerator Res Org KEK, Photon Factory, Inst Mat Struct Sci, Tsukuba, Ibaraki 3050801, Japan
[2] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan
[3] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitech, Tsukuba, Ibaraki 3050044, Japan
[4] JASRI SPring 8, Hyogo 6795198, Japan
[5] Grad Univ Adv Studies, Tsukuba, Ibaraki 3050801, Japan
来源
SRI 2009: THE 10TH INTERNATIONAL CONFERENCE ON SYNCHROTRON RADIATION INSTRUMENTATION | 2010年 / 1234卷
关键词
PEEM; x-ray absorption spectroscopy; two-dimensional nanomaterials; FILMS;
D O I
10.1063/1.3463234
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have demonstrated x-ray nanospectroscopy for two-dimensional nanomaterials with attogram (=10(-18) gram) weight samples. The x-ray nanospectroscopic characterization of the nanomaterials was performed using SPELEEM (Spectroscopic Photoemission and Low Energy Electron Microscopy) at BL17SU of the SPring-8 in Japan. For quantitative x-ray absorption spectroscopy analysis with high spatial resolution and high stability during the photon energy scan, we have implemented a sample drift correction and a uniform lighting correction by image analysis. Using these corrections, the x-ray absorption spectra from 80 nm x 80 nm area are significantly improved and the layer-dependent electronic structure analysis is also demonstrated.
引用
收藏
页码:437 / +
页数:2
相关论文
共 10 条
[1]  
Haralick R.M., 1992, Computer and Robot Vision, V2, P316
[2]   X-ray nanospectroscopic characterization of a molecularly thin ferromagnetic Ti1-xCoxO2 nanosheet [J].
Kotani, Yoshinori ;
Taniuchi, Toshiyuki ;
Osada, Minoru ;
Sasaki, Takayoshi ;
Kotsugi, Masato ;
Guo, F. Z. ;
Watanabe, Yoshio ;
Kubota, Masato ;
Ono, Kanta .
APPLIED PHYSICS LETTERS, 2008, 93 (09)
[3]   Recent advances in chemical and magnetic imaging of surfaces and interfaces by XPEEM [J].
Locatelli, A. ;
Bauer, E. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2008, 20 (09)
[4]   Fabrication of densely packed titania nanosheet films on solid surface by use of Langmuir-Blodgett deposition method without amphiphilic additives [J].
Muramatsu, M ;
Akatsuka, K ;
Ebina, Y ;
Wang, KZ ;
Sasaki, T ;
Ishida, T ;
Miyake, K ;
Haga, M .
LANGMUIR, 2005, 21 (14) :6590-6595
[5]   Two-dimensional gas of massless Dirac fermions in graphene [J].
Novoselov, KS ;
Geim, AK ;
Morozov, SV ;
Jiang, D ;
Katsnelson, MI ;
Grigorieva, IV ;
Dubonos, SV ;
Firsov, AA .
NATURE, 2005, 438 (7065) :197-200
[6]  
Ohashi H, 2007, AIP CONF PROC, V879, P523
[7]   Exfoliated oxide nanosheets: new solution to nanoelectronics [J].
Osada, Minoru ;
Sasaki, Takayoshi .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (17) :2503-2511
[8]   Macromolecule-like aspects for a colloidal suspension of an exfoliated titanate. Pairwise association of nanosheets and dynamic reassembling process initiated from it [J].
Sasaki, T ;
Watanabe, M ;
Hashizume, H ;
Yamada, H ;
Nakazawa, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (35) :8329-8335
[9]   Semiconductor nanosheet crystallites of quasi-TiO2 and their optical properties [J].
Sasaki, T ;
Watanabe, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (49) :10159-10161
[10]   Layer-by-layer assembly of titania nanosheet/polycation composite films [J].
Sasaki, T ;
Ebina, Y ;
Tanaka, T ;
Harada, M ;
Watanabe, M ;
Decher, G .
CHEMISTRY OF MATERIALS, 2001, 13 (12) :4661-4667