One-step catalytic conversion of ethanol into 1,3-butadiene using zinc-containing talc

被引：45

作者：

Sekiguchi, Yasumasa ^{[1
,2
]}

Akiyama, Sohta ^{[1
]}

Urakawa, Wataru ^{[1
]}

Koyama, To-ru ^{[1
]}

Miyaji, Akimitsu ^{[1
]}

Motokura, Ken ^{[1
]}

Baba, Toshihide ^{[1
]}

机构：

[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Environm Chem & Engn, Midori Ku, Yokohama, Kanagawa 2268502, Japan

[2] Press Kogyo Co Ltd, Kawasaki, Kanagawa 2108512, Japan

来源：

CATALYSIS COMMUNICATIONS | 2015年 / 68卷

关键词：

Ethanol; 1,3-Butadiene; Zinc-containing talc; High production rate; BUTADIENE FORMATION; SEPIOLITE;

D O I：

10.1016/j.catcom.2015.04.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Compared with previously reported catalysts, zinc-containing talc exhibited the highest formation rate of 1,3-butadiene in one-step conversion of ethanol at 673 K. Our results showed that talc containing just 1.4 wt.% of ZnO produced 1,3-butadiene at a rate of 1.9 x 10(-2) mol g(-1) h(-1). (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：20 / 24

页数：5

共 13 条

[11] PRONOUNCED CATALYTIC ACTIVITY AND SELECTIVITY OF MGO-SIO2-NA2O FOR SYNTHESIS OF BUTA-1,3-DIENE FROM ETHANOL [J].