Synthesis, crystal structure and fluorescent properties of indolo[3,2-b]carbazole-based metal-organic coordination polymers

被引：8
作者：
Khan, Il Son [1 ,2 ]
Samsonenko, Denis G. [1 ,2 ]
Irgashev, Roman A. [3 ,4 ]
Kazin, Nikita A. [3 ]
Rusinov, Gennady L. [3 ,4 ]
Charushin, Valery N. [3 ,4 ]
Zavakhina, Marina S. [1 ,2 ]
Fedin, Vladimir P. [1 ,2 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
[3] Russian Acad Sci, Ural Branch, Postovsky Inst Organ Synth, Ekaterinburg, Russia
[4] Ural Fed Univ, Ekaterinburg, Russia
来源：
POLYHEDRON | 2018年 / 141卷
基金：
俄罗斯科学基金会;
关键词：
Metal-organic framework; Coordination polymer; Indolo[3,2-b]carbazoles; Zinc complexes; Luminescence; FRAMEWORKS; MOFS;
D O I：
10.1016/j.poly.2017.12.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 5,11-dihydroindolo[3,2-b]carbazole-based bidentate ligand bearing two carboxylic groups, (3,3'-(indolo[3,2-b]carbazole-5,11-diyl)dipropionic acid, H(2)icdc), has been synthesized in two steps and then used for the construction of two metal organic coordination polymers, namely [Zn-3(dmf)(2)(icdc)(3)]center dot 4DMF (1) and [Zn-2(dabco)(icdc)(2)]center dot 4NMP center dot 4H(2)O (2) (dabco = 1,4-diazabicyclo[2.2.2]octane, DMF = N,N-dimethylformamide, NMP = N-methyl-2-pyrrolidone). Compound 1 has a layered structure, while compound 2 has a 3D framework structure. Both compounds display linker-based blue fluorescence. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：337 / 342
页数：6
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