Synthesis, spectroscopic characterization, X-ray crystal structure and magnetic properties of dinuclear copper(II) complex with dual end-to-end and end-on cyanate bridges:: [Cu2(μ-NCO-N,N′)2(NCO-N)2(dpyam)2]

被引：31
作者：
Youngme, S [1 ]
Phatchimkun, J
Suksangpanya, U
Pakawatchai, C
van Albada, GA
Reedijk, J
机构：
[1] Khon Kaen Univ, Fac Sci, Dept Chem, Khon Kaen 40002, Thailand
[2] Prince Songkla Univ, Fac Sci, Dept Chem, Hat Yai 90112, Thailand
[3] Leiden Univ, Gorlaeus Labs, Inst Chem, NL-2300 RA Leiden, Netherlands
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 10期
关键词：
copper(II); pseudohalides; EPR; magnetism; di-2-pyridylamine; cyanate;
D O I：
10.1016/j.inoche.2005.06.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new dinuclear copper(II) complex [Cu-2(mu(1),(1)-NCO)(2)(NCO)(2)(dpyam)(2)] (dpyam = di-2-pyridylamine) has been synthesized and characterized by X-ray diffraction. Two N-bonded cyanato ligands bridge two copper ions in an end-on fashion and two others act as the N-bonded terminal ligands. The copper ion has a distorted square-pyramidal environment. The magnetic susceptibility, measured from 5 to 300 K, has revealed a weak ferromagnetic interaction between the Cu(II) atoms with a singlet-triplet energy gap (J) of 6.03 cm(-1). The EPR spectrum, measured as a powdered solid at RT and 77 K, shows an S = 1/2 signal with g(perpendicular to) = 2.08 and an unresolved g(parallel to) of 2.29. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：882 / 885
页数：4
相关论文
共 50 条
[31]   X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide [J].
Ellena, J. ;
Kremer, E. ;
Facchin, G. ;
Baran, E. J. ;
Nascimento, O. R. ;
Costa-Filho, A. J. ;
Torre, M. H. .
POLYHEDRON, 2007, 26 (13) :3277-3285
[32]   Synthesis, Characterization and Crystal Structure of an Unstable Dinuclear Azido-Bridged Nickel(II) Complex [Ni2(C12H15Br2N2O)2(1,1-N3)2(CH3CN)2] 2CH3CN [J].
Lin, Hong-Wei .
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2009, 39 (01) :9-12
[33]   Synthesis, structure and redox properties of an unexpected trinuclear copper(II) complex with aspartame:: [Cu(apm)2Cu(μ-N,O:O′-apm)2(H2O)Cu(apm)2(H2O)]•5H2O [J].
Cavicchioli, M ;
Massabni, AC ;
Ferreira, AMD ;
Castellano, EE ;
Crespi, MS .
INORGANICA CHIMICA ACTA, 2005, 358 (15) :4431-4436
[34]   A copper(II) chain compound with hydrogenphosphate bridges organized in a double-chain structure.: Synthesis, structure and magnetic properties of [Cu(1,10-phenanthroline)(μ-HPO4)(H2O)2]n [J].
Youngme, S ;
Phuengphai, P ;
Pakawatchai, C ;
van Albada, GA ;
Tanase, S ;
Mutikainen, P ;
Turpeinen, U ;
Reedijk, J .
INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (04) :335-338
[35]   Coordination properties of ethyl bis(pyridin-2-ylmethyl)phosphate ligand with copper and zinc chloride. X-ray crystal structure of Cu(II) complex [J].
Kalinowska-Lis, Urszula ;
Zurowska, Bogumila ;
Slepokura, Katarzyna ;
Ochocki, Justyn .
INORGANICA CHIMICA ACTA, 2011, 376 (01) :18-22
[36]   Polymer species in aqueous solutions of para-phenylenediamine-N,N,N',N'-tetraacetic acid (p-PhDTA) with cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II). X-ray crystal structure of Na-4[Co-2(p-PhDTA)(2)]center dot 8H(2)O [J].
Gonzalez, CA ;
HernandezPadilla, M ;
Dominguez, S ;
Mederos, A ;
Brito, F ;
Arrieta, JM .
POLYHEDRON, 1997, 16 (17) :2925-2940
[37]   Synthesis, X-ray crystal structures and magnetic properties of Cu(II)(NITpPy)2[N(CN)2]2•solv (NITpPy = nitronyl nitroxide radical, solv = H2O or CH3CN).: From discrete molecules to 2-D polymeric coordination compounds [J].
Dasna, I ;
Golhen, S ;
Ouahab, L ;
Fettouhi, M ;
Pena, O ;
Daro, N ;
Sutter, JP .
INORGANICA CHIMICA ACTA, 2001, 326 (01) :37-46
[38]   Synthesis and spectroscopic characterisation of copper(II) complexes with 5-methyl-1-(2′-pyridyl) pyrazole-3-carboxamide (MPyPzCA):: X-ray crystal structure of [Cu(MPyPzCA)2(H2O)](ClO4)2 [J].
Adhikari, N ;
Chaudhuri, S ;
Butcher, RJ ;
Saha, N .
POLYHEDRON, 1999, 18 (8-9) :1323-1328
[39]   Asymmetric bis-(μ1,1-azido) bridged dinuclear copper(II) complex with N2O donor Schiff base: synthesis, structure and magnetic study [J].
Das, Mithun ;
Shaw, Bikash Kumar ;
Ghosh, Biswa Nath ;
Rissanen, Kari ;
Saha, Shyamal Kumar ;
Chattopadhyay, Shouvik .
JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (08) :1361-1373
[40]   Synthesis, characterization, and X-ray structure of n′-(2-hydroxy-5-methylbenzylidene)-4-trifluoromethylbenzohydrazide and its dioxidomolybdenum(vi) complex with catalytic property [J].
Liang, Peng ;
Hong, Zhe .
INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (06) :950-955
12345