Terminal hydridozinc cation

被引：21

作者：

Chambenahalli, Raju ^{[1
]}

Andrews, Alex P. ^{[1
]}

Ritter, Florian ^{[2
]}

Okuda, Jun ^{[2
]}

Venugopal, Ajay ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res Thiruvananthapuram, Sch Chem, Thiruvananthapuram 695551, Kerala, India

[2] Rhein Westfal TH Aachen, Inst Inorgan Chem, Landoltweg 1, D-52056 Aachen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 14期

关键词：

HOMOGENEOUS CATALYTIC-REDUCTION; ZINC HYDRIDE; COMPLEXES; CO2; REACTIVITY; HYDROSILYLATION; POLYMERIZATION; COORDINATION; LIGAND;

D O I：

10.1039/c8cc09839e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A thermally stable terminal hydridozinc cation has been isolated. The nucleophilicity of the hydride ligand is demonstrated by inserting carbon dioxide, carbodiimide and benzophenone across the Zn-H bond in a facile manner. Preliminary studies on catalytic hydrosilylation using PhSiH3 indicate that the hydridozinc cation in the presence of BPh3 can selectively reduce CO2 to PhSi(OCHO)(3).

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页码：2054 / 2057

页数：4

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