Stability of metal-organic frameworks under gamma irradiation

被引：88

作者：

Volkringer, C. ^{[1
,2
]}

Falaise, C. ^{[1
]}

Devaux, P. ^{[1
]}

Giovine, R. ^{[1
]}

Stevenson, V. ^{[1
]}

Pourpoint, F. ^{[1
]}

Lafon, O. ^{[1
]}

Osmond, M. ^{[3
]}

Jeanjacques, C. ^{[3
]}

Marcillaud, B. ^{[3
]}

Sabroux, J. C. ^{[3
]}

Loiseau, T. ^{[1
]}

机构：

[1] Univ Lille, ENSCL, CNRS, UCCS,UMR 8181, Bat C7,BP 90108, F-59652 Villeneuve Dascq, France

[2] Inst Univ France, 1 Rue Descartes, F-75231 Paris 05, France

[3] Ctr Saclay, PSN RES SCA, IRSN, F-91192 Gif Sur Yvette, France

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 84期

关键词：

CAPTURE; IODINE; ADSORPTION; SORPTION;

D O I：

10.1039/c6cc06878b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the study of the resistance of archetypal MOFs (MILs, HKUST-1, UiO-66, and ZIF-8) under gamma irradiation. The different porous solids were irradiated with doses up to 1.75 MGy. All the MOFs constructed with transition metals (Cu2+, Zn2+, Zr4+) exhibit an evident destruction of the framework, whereas the compounds constructed with aluminium remain intact.

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页码：12502 / 12505

页数：4

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