Protonated iron-phthalocyanine complex used for cathode material of a hydrogen peroxide fuel cell operated under acidic conditions

被引：144

作者：

Yamada, Yusuke ^{[1
]}

Yoshida, Sho ^{[1
]}

Honda, Tatsuhiko ^{[1
]}

Fukuzumi, Shunichi ^{[1
,2
]}

机构：

[1] Osaka Univ, Japan Sci & Technol Agcy JST, Dept Mat & Life Sci, Div Adv Sci & Biotechnol,Grad Sch Engn,ALCA, Osaka 5650871, Japan

[2] Ewha Womans Univ, Dept Bioinspired Sci, Seoul 120750, South Korea

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2011年 / 4卷 / 08期

关键词：

HORSERADISH-PEROXIDASE; REDUCTION; OXYGEN; ELECTROCATALYSTS; ELECTRODES; STORAGE; PLANET;

D O I：

10.1039/c1ee01587g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An iron-phthalocyanine complex was utilized as a cathode for constructing a one-compartment hydrogen peroxide fuel cell operated under acidic conditions for the first time. The protonation to the phthalocyanine ligand is crucial to exhibit high activity toward hydrogen peroxide reduction. Nafion (R) coating of the anode improved the stability of the fuel cell.

引用

页码：2822 / 2825

页数：4

共 19 条

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