Thermally Induced Fullerene Domain Coarsening Process in Organic Solar Cells

被引：17
作者：
Agresti, Antonio [1 ,2 ]
Pescetelli, Sara [1 ]
Busby, Yan [3 ]
Aernouts, Tom [2 ]
机构：
[1] Univ Roma Tor Vergata, Elect Engn Dept, I-00133 Rome, Italy
[2] IMEC, PV Dept, Thin Film Photovolta Grp, B-3001 Leuven, Belgium
[3] Univ Namur, Namur Inst Structured Matter, Lab Interdisciplinaire Spectroscopie Elect, B-5000 Namur, Belgium
来源：
IEEE TRANSACTIONS ON ELECTRON DEVICES | 2019年 / 66卷 / 01期
关键词：
Burn-in effect; degradation mechanisms; organic solar cells (OSCs) stability; spectroelectrochemical characterization techniques; OPEN-CIRCUIT VOLTAGE; C-60; FILMS; RAMAN; EFFICIENCY; PEROVSKITE; STABILITY; RECOMBINATION; INTERFACES; DIMER; TRANSFORMATION;
D O I：
10.1109/TED.2018.2880760
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
The recent advancements in power conversion efficiency for organic solar cells is still complained by their reliability and stability remaining the main bottlenecks for organic photovoltaics large scale production and commercialization. In this paper, we aim to provide further insights understanding in degradation processes affecting stability in small molecule flat heterojunction (Glass/ITO/MoO3/ZnPc/C-60/BCP/Ag) solar cells through a systematic aging study coupled with optoelectrical characterizations. In particular, the burn-in phenomenon affecting short-circuit current in thermal-stressed samples has been clearly correlated with the C-60 domain coarsening process and eventually to the decreased exciton lifetime.
引用
收藏
页码：678 / 688
页数：11
相关论文
共 75 条
[1]   Organic Solar Cells: A Review of Materials, Limitations, and Possibilities for Improvement [J].
Abdulrazzaq, Omar A. ;
Saini, Viney ;
Bourdo, Shawn ;
Dervishi, Enkeleda ;
Biris, Alexandru S. .
PARTICULATE SCIENCE AND TECHNOLOGY, 2013, 31 (05) :427-442
[2]  
Agresti A, 2017, IEEE CONF NANOTECH, P145, DOI 10.1109/NANO.2017.8117278
[3]   Micro-Raman analysis of reverse bias stressed dye-sensitized solar cells [J].
Agresti, A. ;
Pescetelli, S. ;
Quatela, A. ;
Mastroianni, S. ;
Brown, T. M. ;
Reale, A. ;
Bignozzi, C. A. ;
Caramori, S. ;
Di Carlo, A. .
RSC ADVANCES, 2014, 4 (24) :12366-12375
[4]   Graphene Interface Engineering for Perovskite Solar Modules: 12.6% Power Conversion Efficiency over 50 cm2 Active Area [J].
Agresti, Antonio ;
Pescetelli, Sara ;
Palma, Alessandro L. ;
Castillo, Antonio E. Del Rio ;
Konios, Dimitrios ;
Kakavelakis, Geore ;
Razza, Stefano ;
Cina, Lucio ;
Kymakis, Emmanuel ;
Bonaccorso, Francesco ;
Di Carlo, Aldo .
ACS ENERGY LETTERS, 2017, 2 (01) :279-287
[5]   Graphene-Perovskite Solar Cells Exceed 18% Efficiency: A Stability Study [J].
Agresti, Antonio ;
Pescetelli, Sara ;
Taheri, Babak ;
Castillo, Antonio Esau Del Rio ;
Cina, Lucio ;
Bonaccorso, Francesco ;
Di Carlo, Aldo .
CHEMSUSCHEM, 2016, 9 (18) :2609-2619
[6]   Stability of dye-sensitized solar cell under reverse bias condition: Resonance Raman spectroscopy combined with spectrally resolved analysis by transmittance and efficiency mapping [J].
Agresti, Antonio ;
Cina, Lucio ;
Pescetelli, Sara ;
Taheri, Babak ;
Di Carlo, Aldo .
VIBRATIONAL SPECTROSCOPY, 2016, 84 :106-117
[7]   Efficiency and Stability Enhancement in Perovskite Solar Cells by Inserting Lithium-Neutralized Graphene Oxide as Electron Transporting Layer [J].
Agresti, Antonio ;
Pescetelli, Sara ;
Cina, Lucio ;
Konios, Dimitrios ;
Kakavelakis, George ;
Kymakis, Emmanuel ;
Di Carlo, Aldo .
ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (16) :2686-2694
[8]  
Agresti A, 2015, 2015 IEEE 15TH INTERNATIONAL CONFERENCE ON NANOTECHNOLOGY (IEEE-NANO), P732, DOI 10.1109/NANO.2015.7388712
[9]   Polyiodides formation in solvent based Dye Sensitized Solar Cells under reverse bias stress [J].
Agresti, Antonio ;
Pescetelli, Sara ;
Gatto, Emanuela ;
Venanzi, Mariano ;
Di Carlo, Aldo .
JOURNAL OF POWER SOURCES, 2015, 287 :87-95
[10]   Triplet state dissociation of C120, the dimer of C60 [J].
Bachilo, SM ;
Benedetto, AF ;
Weisman, RB .
JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (43) :9845-9850
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