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High-resolution x-ray diffraction study of single crystals of lead zirconate titanate
被引:60
作者:

Gorfman, S.
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Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

Keeble, D. S.
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Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

Glazer, A. M.
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Univ Oxford, Dept Phys, Clarendon Lab, Oxford OX1 3PU, England Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

Long, X.
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机构:
Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada
Simon Fraser Univ, LABS 4D, Burnaby, BC V5A 1S6, Canada Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

Xie, Y.
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Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada
Simon Fraser Univ, LABS 4D, Burnaby, BC V5A 1S6, Canada Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

Ye, Z-G.
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机构:
Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada
Simon Fraser Univ, LABS 4D, Burnaby, BC V5A 1S6, Canada Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

Collins, S.
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机构:
Diamond Light Source Ltd, Rutherford Appleton Lab, Didcot OX11 0QX, Oxon, England Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

Thomas, P. A.
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Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
机构:
[1] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
[2] Univ Oxford, Dept Phys, Clarendon Lab, Oxford OX1 3PU, England
[3] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada
[4] Simon Fraser Univ, LABS 4D, Burnaby, BC V5A 1S6, Canada
[5] Diamond Light Source Ltd, Rutherford Appleton Lab, Didcot OX11 0QX, Oxon, England
基金:
英国工程与自然科学研究理事会;
关键词:
MONOCLINIC PHASE;
D O I:
10.1103/PhysRevB.84.020102
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
The symmetry of single-crystal piezoelectric PbZr1-xTixO3, with x approximate to 0.31 and x approximate to 0.46, has been investigated by high-resolution x-ray diffraction, both at room temperature and up to and above the Curie temperature. Reciprocal space maps around a selection of Bragg reflections were collected and self-consistent patterns showing Bragg splittings were observed. The analysis of the separation of peaks from different twin domains provides precise information on PbZr1-xTixO3 symmetry when approaching the morphotropic phase boundary at x = 0.48 from the zirconium-rich side.
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