High-resolution x-ray diffraction study of single crystals of lead zirconate titanate

被引:60
作者
Gorfman, S. [1 ]
Keeble, D. S. [1 ]
Glazer, A. M. [2 ]
Long, X. [3 ,4 ]
Xie, Y. [3 ,4 ]
Ye, Z-G. [3 ,4 ]
Collins, S. [5 ]
Thomas, P. A. [1 ]
机构
[1] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
[2] Univ Oxford, Dept Phys, Clarendon Lab, Oxford OX1 3PU, England
[3] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada
[4] Simon Fraser Univ, LABS 4D, Burnaby, BC V5A 1S6, Canada
[5] Diamond Light Source Ltd, Rutherford Appleton Lab, Didcot OX11 0QX, Oxon, England
基金
英国工程与自然科学研究理事会;
关键词
MONOCLINIC PHASE;
D O I
10.1103/PhysRevB.84.020102
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The symmetry of single-crystal piezoelectric PbZr1-xTixO3, with x approximate to 0.31 and x approximate to 0.46, has been investigated by high-resolution x-ray diffraction, both at room temperature and up to and above the Curie temperature. Reciprocal space maps around a selection of Bragg reflections were collected and self-consistent patterns showing Bragg splittings were observed. The analysis of the separation of peaks from different twin domains provides precise information on PbZr1-xTixO3 symmetry when approaching the morphotropic phase boundary at x = 0.48 from the zirconium-rich side.
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页数:4
相关论文
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