Polypropylene/graphene nanoplatelets nanocomposites with high conductivity via solid-state shear mixing

The research on facile, low-cost, and green process for the uniform dispersion of graphene nanoplatelets (GNPs) into polymer matrix has always been a considerable challenge in practical applications. The Van der Waals interaction between graphene layers can easily cause aggregation of the nanofillers. Here, we propose a new method to solve this problem by involving solid-state shear mixing to obtain a well-dispersed nanocomposite. The comprehensive properties of nanocomposite, including antistatic properties, mechanical properties, and thermal stability, can be significantly enhanced by this method. The surface resistivity of the nanocomposite can be up to 2.4 x 10(7) Omega sq(-1) under 1 wt% content of GNPs, which is significantly better than the value obtained by conventional melting compounding and meets the required standard of less than 3 x 10(8) Omega sq(-1) for actual application antistatic materials. The impact strength of the nanocomposite increased by 120.8% when compared with neat PP. At the same time, the heat distortion temperature and initial decomposition temperature of the nanocomposite with only 0.5wt% content of GNPs are improved by 11.7 degrees C and 110 degrees C, respectively. In addition, GNPs is a heterogeneous nucleating agent that leads PP to emerge beta crystal form. This study provides an effective and practical reference for the broadscale industrial preparation of polymer-based graphene nanocomposites.