Ionic Liquids with a Twist: New Routes to Liquid Salts

被引：33
作者：
Giernoth, Ralf [1 ]
机构：
[1] Univ Cologne, Dept Chem, D-50939 Cologne, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 33期
关键词：
electronic effects; fatty acids; ionic liquids; steric effect; HOMEOVISCOUS ADAPTATION; PHYSICAL-PROPERTIES; PREDICT;
D O I：
10.1002/anie.201002393
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Melting without heat: Attempts to design new ionic liquids (often functionalized) often lead to only "ionic solids". Two recent studies demonstrate very promising and viable ways to "liquify" systems that are based on the common structural motifs that still dominate the literature (see picture; Tf2N-= bis(trifluoromethylsulfonyl)imide. © 2010 Wiley-VCH Verlag GmbH & Co. KCaA, Weinheim.
引用
收藏
页码：5608 / 5609
页数：2
相关论文
共 14 条
[11]   The Fluid-Mosaic Model, Homeoviscous Adaptation, and Ionic Liquids: Dramatic Lowering of the Melting Point by Side-Chain Unsaturation [J].
Murray, Samuel M. ;
O'Brien, Richard A. ;
Mattson, Kaila M. ;
Ceccarelli, Christopher ;
Sykora, Richard E. ;
West, Kevin N. ;
Davis, James H., Jr. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (15) :2755-2758
[12]   HOMEOVISCOUS ADAPTATION - HOMEOSTATIC PROCESS THAT REGULATES VISCOSITY OF MEMBRANE LIPIDS IN ESCHERICHIA-COLI [J].
SINENSKY, M .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1974, 71 (02) :522-525
[13]   How to predict the physical properties of ionic liquids: A volume-based approach [J].
Slattery, John M. ;
Daguenet, Corinne ;
Dyson, Paul J. ;
Schubert, Thomas J. S. ;
Krossing, Ingo .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (28) :5384-5388
[14]  
Wasserscheid P., 2007, Ionic Liquids in Synthesis, V1
12