Interconnected honeycomb-like porous carbon derived from plane tree fluff for high performance supercapacitors

被引:85
|
作者
Zhang, Yunqiang [1 ]
Liu, Xuan [2 ]
Wang, Shulan [1 ]
Dou, Shixue [3 ]
Li, Li [4 ]
机构
[1] Northeastern Univ, Sch Sci, Dept Chem, Shenyang 110819, Peoples R China
[2] Carnegie Mellon Univ, Dept Mat Sci & Engn, Pittsburgh, PA 15213 USA
[3] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
[4] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14850 USA
基金
中国国家自然科学基金; 澳大利亚研究理事会;
关键词
CAPACITIVE ENERGY-STORAGE; REDUCED GRAPHENE OXIDE; ELECTROCHEMICAL CAPACITORS; ELECTRODE MATERIALS; MESOPOROUS CARBON; ACTIVATED CARBONS; FUNCTIONAL-GROUPS; FACILE SYNTHESIS; HUMAN HAIR; NITROGEN;
D O I
10.1039/c6ta03826c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Three-dimensional interconnected honeycomb-like porous carbon (IHPC-800) is successfully fabricated via activated and graphitized plane tree fluff with the aid of Co2+ and KOH in a synthetic process at 800 degrees C. The as-prepared IHPC-800 exhibits advantageous structural features for application in supercapacitors (SCs), including interconnected pathways, high specific surface area (1154 m(2) g(-1)), large pore volume (0.78 cm(3) g(-1)), heteroatom doping, and full graphitization. This material possesses a very high charge storage capacity with a specific capacitance of 493 F g(-1) in 2 M H2SO4 in a three-electrode system at a current density of 0.2 A g(-1). It exhibits excellent cycle stability, even over 10 000 cycles with a capacity retention of more than 96%. The energy density of 42.8 W h kg(-1) is also verified with 1 M LiPF6 in EC/DEC as the organic electrolyte at a power density of 299 W kg (1). The excellent electrochemical performance and facile effective synthesis of bio-derived carbon materials point to an economical and feasible strategy for the large-scale production of high performance SCs.
引用
收藏
页码:10869 / 10877
页数:9
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