Synthesis, properties, and practical application of hyperbranched polymers

被引:36
|
作者
Korolev, G. V. [1 ]
Bubnova, M. L. [1 ]
机构
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
基金
俄罗斯基础研究基金会;
关键词
TRANSFER RADICAL POLYMERIZATION; BB'(2) TYPE MONOMERS; CONDENSING VINYL POLYMERIZATION; ETHYLENE-GLYCOL DIMETHACRYLATE; MOLECULAR-SIZE DISTRIBUTION; ONE-STEP SYNTHESIS; BRANCHED POLY(METHYL METHACRYLATE)S; ONE-POT SYNTHESIS; CRITICAL CONVERSION; PERFLUORINATED POLY(PHENYLENEGERMANE);
D O I
10.1134/S1811238207040030
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The methods of synthesis of hyperbranched polymers are considered and systematized with main attention focused on such modern and promising procedures of crosslinking free-radical polymerization as living chain and intense chain transfer regimes. The synthetic approach to hyperbranched polymers via free-radical oxidative polymerization is the first to be put forth. The main problems concerning these polymers are formulated, and the recent advances in this field are generalized and elucidated.
引用
收藏
页码:332 / 354
页数:23
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