Collector Phase Transitions during Vapor-Solid-Solid Nucleation of GaN Nanowires

被引:39
作者
Cheze, Caroline [1 ,2 ]
Geelhaar, Lutz [1 ,2 ]
Trampert, Achim [1 ]
Brandt, Oliver [1 ]
Riechert, Henning [1 ,2 ]
机构
[1] Paul Drude Inst Festkorperelekt, D-10117 Berlin, Germany
[2] Qimonda, D-81730 Munich, Germany
关键词
nanowire; nanocolumn; nucleation; molecular beam epitaxy; nitrides; NI; GROWTH; MECHANISM; EQUILIBRIA; EXPANSION;
D O I
10.1021/nl101465b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We investigate the nucleation of Ni-induced GaN nanowires by in situ and ex situ experiments. Three nucleation stages are evidenced. in the first two stages, different crystal structures of the Ni collectors are identified. Real-time monitoring of the Ga desorption allows the amount of Ga incorporated in the collectors to be quantified. A transition of their crystal structure prior to nanowire growth is found to be in agreement with the thermodynamically stable phase sequence of the relevant phase diagrams.
引用
收藏
页码:3426 / 3431
页数:6
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