Heterogeneous yielding dynamics in a colloidal gel

被引:120
作者
Gibaud, Thomas [1 ,2 ]
Frelat, Damien [1 ]
Manneville, Sebastien [1 ]
机构
[1] Univ Lyon, Phys Lab, CNRS, Ecole Normale Super Lyon,UMR 5672, F-69364 Lyon 07, France
[2] Brandeis Univ, Dept Phys, Waltham, MA 02453 USA
关键词
GLASSY MATERIALS; RHEOLOGY; BEHAVIOR; FRACTURE; FLUIDS; FLOW; DISPERSIONS; SUSPENSIONS; PARTICLES; STRESS;
D O I
10.1039/c000886a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Attractive colloidal gels display a solid-to-fluid transition as shear stresses above the yield stress are applied. This shear-induced transition is involved in virtually any application of colloidal gels. It is also crucial for controlling material properties. Still, the yielding transition is far from understood, mainly because rheological measurements are spatially averaged over the whole sample. We use high-frequency ultrasound during creep and oscillatory shear experiments to observe the local dynamics of opaque attractive colloidal gels. The transition proceeds from the cell walls and heterogeneously fluidizes the whole sample with a characteristic time that exponentially decreases with the applied stress. The present results reveal the importance of activated processes for the gel dynamics and raise a number of open questions in the attempt to better understand the yielding transition.
引用
收藏
页码:3482 / 3488
页数:7
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