New N-vinylamide-based polymers for the preconcetration of nitrophenols from aqueous media

被引：6

作者：

Churilina, E. V. ^{[1
]}

Sukhanov, P. T. ^{[1
]}

Ermak, S. S. ^{[2
]}

Korenman, Ya I. ^{[1
]}

Shatalov, G. V. ^{[2
]}

机构：

[1] Voronezh State Univ Engn Technol, Voronezh 394036, Russia

[2] Voronezh State Univ, Dept Chem, Voronezh 394693, Russia

来源：

JOURNAL OF ANALYTICAL CHEMISTRY | 2012年 / 67卷 / 09期

关键词：

polymers; N-vinyl amides; nitrophenols; preconcentration; IMPRINTED POLYMERS;

D O I：

10.1134/S1061934812050048

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

New cross-linked copolymer with molecular imprints of 4-nitrophenol have been synthesized by the radical polymerization of cyclic N-vinyl amides and ethylene glycol dimethacrylate. Sorption characteristics of the obtained polymers depend on the nature of the functional monomer, ratio of components in the prepolymerization mixture, pH of solution, and temperature. It has been established that N-vinylpyrrolidone-based copolymers provide higher selectivity of 4-nitrophenol extraction than N-vinylcaprolactam-based products.

引用

页码：767 / 771

页数：5

共 13 条

[1] [Anonymous], 2004, New Reference Book for Chemist and Technologist. Electrode Processes. Chemical Kinetics and Diffusion
[2] Effective systems based on hydrophilic polymers for extraction of phenols from aqueous solutions
Churilina, E. V.
Sukhanov, P. T.
Korenman, Ya. I.
Shatalov, G. V.
[J]. RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2010, 83 (06) : 1054 - 1058
[3] Churilina E.V., 2010, MIRE NAUCHNYKH OTKRY, P99
[4] [Дмитриенко С.Г. Dmitrienko S.G.], 2006, [Вестник Московского университета. Серия 2: Химия, Vestnik Moskovskogo universiteta. Seriya 2: Khimiya], V47, P210
[5] Synthesis and study of the sorption properties of 4-hydroxybenzoic acid-imprinted polymers
Dmitrienko, SG
Irkha, VV
Duisebaeva, TB
Mikhailik, YV
Zolotov, YA
[J]. JOURNAL OF ANALYTICAL CHEMISTRY, 2006, 61 (01) : 14 - 19
[6] Use of molecular imprinted polymers for the separation and preconcentration of organic compounds
Dmitrienko, SG
Irkha, VV
Kuznetsova, AY
Zolotov, YA
[J]. JOURNAL OF ANALYTICAL CHEMISTRY, 2004, 59 (09) : 808 - 817
[7] Gendrikson O.D., 2006, Usp. Biol. Khim, V46, P149
[8] Houben-Weyl I., 1953, METHODEN ORG CHEM, V2
[9] Kazitsyna L. A., 1971, PRIMENENIE UF IK YAM
[10] Kirsh YuE., 1998, POLY N VINYLPYRROLID

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