Yttrium-doped alumoxanes: A chimie douce route to Y3Al5O12 (YAG) and Y4Al2O9 (YAM)

被引：48

作者：

Harlan, CJ

Kareiva, A

MacQueen, DB

Cook, R

Barron, AR

机构：

[1] RICE UNIV,DEPT CHEM,HOUSTON,TX 77005

[2] RICE UNIV,DEPT MECH ENGN & MAT SCI,HOUSTON,TX 77005

[3] TDA RES INC,WHEAT RIDGE,CO 80033

来源：

ADVANCED MATERIALS | 1997年 / 9卷 / 01期

关键词：

D O I：

10.1002/adma.19970090116

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Yttrium-doped alumoxanes are demonstrated to be ideal precursors for ternary aluminum oxides such as yttrium aluminum garnet (YAG). The yttrium-doped alumoxanes (see Figure), formed by the reaction of carboxylate alumoxanes with Y(acac)(3) (acac = acetylacetonate), provide a chimie douce route to YAG that directly competes with the traditional sol-gel synthesis and has the additional advantage of greater processability of the pre-ceramic.

引用

页码：68 / &

页数：5