One-Pot Synthesis of (E)-Styryl Ketones from Styrenes

被引:22
|
作者
Pawluc, Piotr [1 ]
Szudkowska, Justyna [1 ]
Hreczycho, Grzegorz [1 ]
Marciniec, Bogdan [1 ]
机构
[1] Adam Mickiewicz Univ, Fac Chem, Dept Organometall Chem, PL-60780 Poznan, Poland
来源
JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 15期
关键词
HIGHLY DIASTEREOSELECTIVE SYNTHESIS; RHODIUM-CATALYZED ACYLATION; ALPHA; BETA-UNSATURATED KETONES; TRANSFER HYDROGENATION; COUPLING REACTIONS; HECK REACTIONS; BASE-FREE; BOND; VINYLSILANES;
D O I
10.1021/jo201036x
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new, efficient protocol for the highly stereo-selective one-pot synthesis of (E)-styryl ketones from styrenes based on sequential ruthenium-catalyzed silylative coupling-rhodium-catalyzed desilylative acylation reactions is reported.
引用
收藏
页码:6438 / 6441
页数:4
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