Phenyl(1-phenylsulfonyl-1H-indol-2-yl)methanone

被引:2
作者
Ranjith, S. [1 ]
SubbiahPandi, A. [1 ]
Govindan, E. [1 ]
Dhayalan, V. [2 ]
MohanaKrishnan, A. K. [2 ]
机构
[1] Presidency Coll Autonomous, Dept Phys, Madras 600005, Tamil Nadu, India
[2] Univ Madras, Dept Organ Chem, Madras 600025, Tamil Nadu, India
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
D O I
10.1107/S1600536811008439
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, C21H15NO3S, contains two crystallographically independent molecules. As a result of the electron-withdrawing character of the phenylsulfonyl groups, the N-Csp 2 bond lengths are slightly longer than the anticipated value of approximately 1.35 A for N atoms with planar configurations. Both unique S atoms have a distorted tetrahedral configuration. In each molecule, the indole ring system is essentially planar (r.m.s. deviations for all non-H atoms of 0.020 and 0.023 A). In one molecule, the indole ring system makes dihedral angles of 65.7 (8) and 73.4 (8)degrees, respectively, with the benzene and phenyl rings [62.2 (7) and 72.1 (7)degrees, respectively, in the other molecule].
引用
收藏
页码:O844 / U221
页数:12
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