Lanthanide single molecule magnets: progress and perspective

被引:331
作者
Zhang, Peng [1 ,2 ]
Zhang, Li [1 ,2 ]
Tang, Jinkui [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
ANGULAR-RESOLVED MAGNETOMETRY; COUPLING DY-3 TRIANGLES; ION MAGNETS; DILANTHANIDE COMPLEXES; SLOW RELAXATION; NANO-MAGNETS; LOW-SYMMETRY; ANISOTROPY; BLOCKING; MAGNETIZATION;
D O I
10.1039/c4dt03329a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The last few years have seen a huge renaissance in the study of single molecule magnets (SMMs) thanks to the extensive applications of lanthanide ions with large inherent anisotropy in molecular magnetism. Particularly, the recent theoretical developments and the experimental expansion into the organometallic avenue have led to an eye-catching boost in this field. Here we highlight the recent progress in this fascinating and challenging field, with emphasis on several combined experimental and theoretical studies.
引用
收藏
页码:3923 / 3929
页数:7
相关论文
共 56 条
[1]   Two pyrazolylborate dysprosium(III) and neodymium(III) single ion magnets modeled by a Radial Effective Charge approach [J].
Baldovi, Jose J. ;
Clemente-Juan, Juan M. ;
Coronado, Eugenio ;
Gaita-Arino, Alejandro .
POLYHEDRON, 2013, 66 :39-42
[2]   Rational Design of Single-Ion Magnets and Spin Qubits Based on Mononuclear Lanthanoid Complexes [J].
Baldovi, Jose J. ;
Cardona-Serra, Salvador ;
Clemente-Juan, Juan M. ;
Coronado, Eugenio ;
Gaita-Arino, Alejandro ;
Palii, Andrew .
INORGANIC CHEMISTRY, 2012, 51 (22) :12565-12574
[3]   Single molecule magnet behaviour in robust dysprosium-biradical complexes [J].
Bernot, Kevin ;
Pointillart, Fabrice ;
Rosa, Patrick ;
Etienne, Mael ;
Sessoli, Roberta ;
Gatteschi, Dante .
CHEMICAL COMMUNICATIONS, 2010, 46 (35) :6458-6460
[4]   Magnetic Anisotropy of Dysprosium(III) in a Low-Symmetry Environment: A Theoretical and Experimental Investigation [J].
Bernot, Kevin ;
Luzon, Javier ;
Bogani, Lapo ;
Etienne, Mael ;
Sangregorio, Claudio ;
Shanmugam, Muralidharan ;
Caneschi, Andrea ;
Sessoli, Roberta ;
Gatteschi, Dante .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (15) :5573-5579
[5]  
Blagg RJ, 2013, NAT CHEM, V5, P673, DOI [10.1038/NCHEM.1707, 10.1038/nchem.1707]
[6]   Angular-Resolved Magnetometry Beyond Triclinic Crystals: Out-of-Equilibrium Studies of Cp*ErCOT Single-Molecule Magnet [J].
Boulon, Marie-Emmanuelle ;
Cucinotta, Giuseppe ;
Liu, Shan-Shan ;
Jiang, Shang-Da ;
Ungur, Liviu ;
Chibotaru, Liviu F. ;
Gao, Song ;
Sessoli, Roberta .
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (41) :13726-13731
[7]   Magnetic Anisotropy and Spin-Parity Effect Along the Series of Lanthanide Complexes with DOTA [J].
Boulon, Marie-Emmanuelle ;
Cucinotta, Giuseppe ;
Luzon, Javier ;
Degl'Innocenti, Chiara ;
Perfetti, Mauro ;
Bernot, Kevin ;
Calvez, Guillaume ;
Caneschi, Andrea ;
Sessoli, Roberta .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (01) :350-354
[8]   An electrostatic model for the determination of magnetic anisotropy in dysprosium complexes [J].
Chilton, Nicholas F. ;
Collison, David ;
McInnes, Eric J. L. ;
Winpenny, Richard E. P. ;
Soncini, Alessandro .
NATURE COMMUNICATIONS, 2013, 4
[9]   Single molecule magnetism in a family of mononuclear β-diketonate lanthanide(III) complexes: rationalization of magnetic anisotropy in complexes of low symmetry [J].
Chilton, Nicholas F. ;
Langley, Stuart K. ;
Moubaraki, Boujemaa ;
Soncini, Alessandro ;
Batten, Stuart R. ;
Murray, Keith S. .
CHEMICAL SCIENCE, 2013, 4 (04) :1719-1730
[10]   Single-molecule magnets [J].
Christou, George ;
Gatteschi, Dante ;
Hendrickson, David N. ;
Sessoli, Roberta .
MRS Bulletin, 2000, 25 (11) :66-71