Stibium: A Promising Electrode toward Building High-Performance Na-Ion Full-Cells

被引：38

作者：

Subramanyan, Krishnan ^{[1
]}

Aravindan, Vanchiappan ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res, Dept Chem, Tirupati 517507, Andhra Pradesh, India

来源：

CHEM | 2019年 / 5卷 / 12期

关键词：

ELECTRICAL ENERGY-STORAGE; SODIUM-ION; LITHIUM-ION; ANODE MATERIAL; SB NANOPARTICLES; ELECTROCHEMICAL PROPERTIES; PYROPHOSPHATE CATHODE; RECHARGEABLE LITHIUM; HOLLOW NANOSPHERES; CARBON NANOFIBERS;

D O I：

10.1016/j.chempr.2019.08.007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Antimony-based materials are promising anode candidates for sodium-ion batteries (NIBs) due to their high theoretical capacity of 660 mAh g(-1) (Na3Sb). In fact, antimony-based alloying and conversion-alloying electrodes exhibit high capacity and cycling stability, with newly developed strategies to overcome the common problem of volume expansion, all leading to renewed interest in antimony-based NIB materials. In this review, we discuss the performance of antimony-based materials for energy storage and conversion devices such as NIBs, Na-ion fuel cells, sea-water batteries, and Na-air batteries. This review also tackles common issues in NIBs that employ antimony-based materials (e.g., Sb-carbon composite and Sb2X3 (X - O, and S), as well as several strategies that can be adopted to address these limitations.

引用

页码：3096 / 3126

页数：31

共 112 条

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