A New Sulfonic Acid-Functionalized Organic Polymer Catalyst for the Synthesis of Biomass-Derived Alkyl Levulinates

被引：30

作者：

Tian, Yi ^{[1
]}

Zhang, Ruoqi ^{[1
]}

Zhao, Wenguang ^{[1
]}

Wen, Sha ^{[1
]}

Xiang, Yanping ^{[1
]}

Liu, Xianxiang ^{[1
]}

机构：

[1] Hunan Normal Univ, Coll Chem & Chem Engn, Key Lab Assembly & Applicat Organ Funct Mol Hunan, Natl & Local Joint Engn Lab New Petrochem Mat & F, Changsha 410081, Peoples R China

来源：

CATALYSIS LETTERS | 2020年 / 150卷 / 12期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

Biomass; Levulinic acid; Alkyl levulinates; Sulfonic acid; Organic polymer; Catalysis; ETHYL LEVULINATE; EFFICIENT CONVERSION; ESTERIFICATION; DEACTIVATION; CELLULOSE;

D O I：

10.1007/s10562-020-03253-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alkyl levulinates are important biobased chemicals with great fuel-blending properties and good reactivity. In this work, a new functionalized nitrogen-containing organic polymer bearing sulfonic acid groups (PDVTA-SO3H) was successfully prepared and studied for the esterification of levulinic acid with alcohols to produce alkyl levulinates. The results showed that this sulfonic acid-functionalized organic polymer possessed high catalytic activity, and the yield of n-butyl levulinate reached 97.4% under the mild conditions. PDVTA-SO3H exhibited strong acidic sites and high stability, and would be well expected to be a potential candidate better than some commercial sulfonic solid catalysts for alkyl levulinates production. The catalyst had been reused without any treatment for five times and the results proved its potential for industrial applications. [GRAPHICS] .

引用

页码：3553 / 3560

页数：8

共 28 条

[1] Production of methyl esters from waste cooking oil using a heterogeneous biomass-based catalyst [J].

Farid, Mohammed Abdillah Ahmad ;

Hassan, Mohd Ali ;

Taufiq-Yap, Yun Hin ;

Ibrahim, Mohd Lokman ;

Othman, Mohd Ridzuan ;

Ali, Ahmad Amiruddin Mohd ;

Shirai, Yoshihito .

RENEWABLE ENERGY, 2017, 114 :638-643

[2] Levulinic acid esterification with ethanol to ethyl levulinate production over solid acid catalysts [J].

Fernandes, D. R. ;

Rocha, A. S. ;

Mai, E. F. ;

Mota, Claudio J. A. ;

Teixeira da Silva, V. .

APPLIED CATALYSIS A-GENERAL, 2012, 425 :199-204

[3]

Fernandes DR, 2011, J ENERGY CHEM, V20, P18

[4] Sulfonated porous organic polymer as a highly efficient catalyst for the synthesis of biodiesel at room temperature [J].

Gomes, Ruth ;

Bhanja, Piyali ;

Bhaumik, Asim .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 411 :110-116

[5] Highly porous organic polymers bearing tertiary amine group and their exceptionally high CO2 uptake capacities [J].

Gomes, Ruth ;

Bhaumik, Asim .

JOURNAL OF SOLID STATE CHEMISTRY, 2015, 222 :7-11

[6] Conversion of cellulose to glucose and levulinic acid via solid-supported acid catalysis [J].

Hegner, Jessica ;

Pereira, Kyle C. ;

DeBoef, Brenton ;

Lucht, Brett L. .

TETRAHEDRON LETTERS, 2010, 51 (17) :2356-2358

[7] Selective cleavage of lignin and lignin model compounds without external hydrogen, catalyzed by heterogeneous nickel catalysts [J].

Jiang, Liang ;

Guo, Haiwei ;

Li, Changzhi ;

Zhou, Peng ;

Zhang, Zehui .

CHEMICAL SCIENCE, 2019, 10 (16) :4458-4468

[8]

Karjanto S, 2016, J TEKNOL, V78, P113

[9] Efficient Conversion of Levulinic Acid to Ethyl Levulinate over a Silicotungstic-Acid-Modified Commercially Silica-Gel Sphere Catalyst [J].

Kong, Xiangjin ;

Wu, Shuxiang ;

Li, Xiaole ;

Liu, Junhai .

ENERGY & FUELS, 2016, 30 (08) :6500-6504

[10] Esterification of levulinic acid with ethanol over sulfated mesoporous zirconosilicates: Influences of the preparation conditions on the structural properties and catalytic performances [J].

Kuwahara, Yasutaka ;

Fujitani, Tadahiro ;

Yamashita, Hiromi .

CATALYSIS TODAY, 2014, 237 :18-28

← 1 2 3 →