"Nanoscale Lattice Fence" in a Metal-Organic Framework: Interplay between Hinged Topology and Highly An isotropic Thermal Response

被引：133

作者：

DeVries, Lucas D. ^{[1
]}

Barron, Paul M. ^{[1
]}

Hurley, Evan P. ^{[1
]}

Hu, Chunhua ^{[3
]}

Choe, Wonyoung ^{[1
,2
]}

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

[2] Univ Nebraska, Nebraska Ctr Mat & Nanosci, Lincoln, NE 68588 USA

[3] NYU, Dept Chem, New York, NY 10003 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 38期

关键词：

COORDINATION POLYMERS; EXPANSION; NETWORK; CDSO4; NETS;

D O I：

10.1021/ja2032822

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A thermoresponsive, 3D hinged metal-organic framework (HMOF-1) assembled from meso-tetra(4-pyridyl)porphine and CdI2 exhibits a 3D "lattice fence" topology with extraordinary thermal expansion and shrinkage. A simple structural model is established to elucidate such a drastic thermal response. The hinged structure model presented here can also be applied to other "lattice fence" topologies with little or no modification, depending on the symmetry of the molecular building blocks.

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收藏

页码：14848 / 14851

页数：4

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