Photosensitized Water Oxidation by Use of a Bioinspired Manganese Catalyst

被引：186

作者：

Karlsson, Erik A. ^{[1
]}

Lee, Bao-Lin ^{[1
]}

Akermark, Torbjorn ^{[2
]}

Johnston, Eric V. ^{[1
]}

Karkas, Markus D. ^{[1
]}

Sun, Junliang ^{[2
]}

Hansson, Orjan ^{[3
]}

Backvall, Jan-E. ^{[1
]}

Akermark, Bjorn ^{[1
]}

机构：

[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden

[2] Stockholm Univ, Arrhenius Lab, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden

[3] Univ Gothenburg, Biophys Grp, Dept Chem, S-40530 Gothenburg, Sweden

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 49期

基金：

欧洲研究理事会;

关键词：

homogeneous catalysis; manganese; N; O ligands; photocatalysis; water oxidation; OXYGEN-EVOLVING CENTER; DINUCLEAR RUTHENIUM COMPLEX; PHOTOSYSTEM-II; SOLAR-ENERGY; MODEL; EVOLUTION; O-2;

D O I：

10.1002/anie.201104355

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Manganificent potential: A dinuclear manganese catalyst contains metal centers that are coordinated by a central phenolate, with adjoining imidazole and carboxylate groups, which are all important functionalities in the natural oxygen-evolving center. The complex catalyzes the conversion of water to oxygen in the presence of a single-electron oxidant [Ru(bpy)3]3+ (see picture, bpy=2,2′-bipyridine, A=acceptor). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11715 / 11718

页数：4

共 38 条

[1] Redox chemistry of a dimanganese(II,III) complex with an unsymmetric ligand:: Water binding, deprotonation and accumulative light-induced oxidation
Anderlund, Magnus F.
Hogblom, Joakim
Shi, Wei
Huang, Ping
Eriksson, Lars
Weihe, Hogni
Styring, Stenbjorn
Akermark, Bjorn
Lomoth, Reiner
Magnuson, Ann
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (24) : 5033 - 5047
[2] Electrochemical and chemical formation of [Mn4IVO5(terpy)4(H2O)2]6+, in relation with the photosystem II oxygen-evolving center model [Mn2III,IVO2(terpy)2(H2O)2]3+
Baffert, C
Romain, S
Richardot, A
Leprêtre, JC
Lefebvre, B
Deronzier, A
Collomb, MN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) : 13694 - 13704
[3] Photochemical conversion of solar energy
Balzani, Vincenzo
Credi, Alberto
Venturi, Margherita
[J]. CHEMSUSCHEM, 2008, 1 (1-2) : 26 - 58
[4] Formation of stoichiometrically 18O-labelled oxygen from the oxidation of 18O-enriched water mediated by a dinuclear manganese complex - a mass spectrometry and EPR study
Beckmann, Katrin
Uchtenhagen, Hannes
Berggren, Gustav
Anderlund, Magnus F.
Thapper, Anders
Messinger, Johannes
Styring, Stenbjorn
Kurz, Philipp
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2008, 1 (06) : 668 - 676
[5] The Ru-Hbpp Water Oxidation Catalyst
Bozoglian, Fernando
Romain, Sophie
Ertem, Mehmed Z.
Todorova, Tanya K.
Sens, Cristina
Mola, Joaquim
Rodriguez, Montserrat
Romero, Isabel
Benet-Buchholz, Jordi
Fontrodona, Xavier
Cramer, Christopher J.
Gagliardi, Laura
Llobet, Antoni
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (42) : 15176 - 15187
[6] Energy resources and global development
Chow, J
Kopp, RJ
Portney, PR
[J]. SCIENCE, 2003, 302 (5650) : 1528 - 1531
[7] Preparation and study of a family of dinuclear Ru(II) complexes that catalyze the decomposition of water
Deng, Zeping
Tseng, Huan-Wei
Zong, Ruifa
Wang, Dong
Thummel, Randolph
[J]. INORGANIC CHEMISTRY, 2008, 47 (06) : 1835 - 1848
[8] Visible Light-Driven Water Oxidation by a Molecular Ruthenium Catalyst in Homogeneous System
Duan, Lele
Xu, Yunhua
Zhang, Pan
Wang, Mei
Sun, Licheng
[J]. INORGANIC CHEMISTRY, 2010, 49 (01) : 209 - 215
[9] Fast Water Oxidation Using Iron
Ellis, W. Chadwick
McDaniel, Neal D.
Bernhard, Stefan
Collins, Terrence J.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (32) : 10990 - 10991
[10] Architecture of the photosynthetic oxygen-evolving center
Ferreira, KN
Iverson, TM
Maghlaoui, K
Barber, J
Iwata, S
[J]. SCIENCE, 2004, 303 (5665) : 1831 - 1838

← 1 2 3 4 →