Synthesis and catalytic activity of nickel(II) complexes of CNC pincer-type N-heterocyclic carbene ligands

被引：21

作者：

Wang, Shuchao ^{[1
]}

Ren, Fang ^{[1
]}

Qiu, Yuping ^{[1
]}

Luo, Meiming ^{[1
]}

机构：

[1] Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem, Chengdu 610064, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2015年 / 788卷

基金：

中国国家自然科学基金;

关键词：

Nickel complex; Pincer-type ligand; N-heterocyclic carbene; Ni(II)-N-heterocyclic carbene complex; Suzuki reaction; CROSS-COUPLING REACTIONS; ARYL CHLORIDES; ARYLBORONIC ACIDS; ORGANOBORON COMPOUNDS; ROOM-TEMPERATURE; PALLADIUM(II) COMPLEXES; HETEROARYL MESYLATES; AROMATIC AMINATIONS; METAL-COMPLEXES; BOND FORMATION;

D O I：

10.1016/j.jorganchem.2015.04.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Air- and moisture-stable nickel(II) complexes 2a-c of CNC pincer-type N-heterocyclic carbene ligands have been prepared from the corresponding imidazolium salts by carbene-transfer reaction of a silver-NHC complex with Ni(DME)Cl-2 (DME = dimethoxylethane). Pincer complexes 2a-c are characterized by mass and NMR spectroscopy. The structure of 2a is also identified by X-ray diffraction analysis. Pincer complex 2a has been shown to be active catalyst for the Suzuki coupling reactions. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：27 / 32

页数：6

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