Synthesis, Crystal Structure and Thermal Property of Dimethyl Phenanthrene-9,10-dicarboxylate

被引：0

作者：

Luo Zai-Gang ^{[1
]}

Liu Qian-Nan ^{[1
]}

Li Rui ^{[1
]}

Xu Xue-Mei ^{[1
]}

机构：

[1] Anhui Univ Sci & Technol, Coll Chem Engn, Huainan 232001, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 39卷 / 05期

关键词：

phenanthrene; synthesis; crystal structure; thermal property; 4+2 BENZANNULATION; ALKYNES; ACIDS;

D O I：

10.14102/j.cnki.0254-5861.2011-2597

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The target compound (C18H14O4) was synthesized and structurally determined by single-crystal X-ray diffraction. The crystal is of monoclinic system, space group P2(1)/n with a = 7.9383(6), b = 19.5083(13), c = 9.4189(7) angstrom, beta = 98.981(2)degrees, C18H14O4, M-r = 294.29, D-c = 1.357 g/cm(3), V = 1440.75(18) angstrom(3), Z = 4, F(000) = 616, mu(MoKa) = 0.096 mm(-1), T = 293(2) K, 3320 independent reflections with 1845 observed ones (I > 2 sigma(I)), R = 0.0529 and wR = 0.1082 with GOF = 1.015 (R = 0.1202 and wR = 0.1278 for all data). The phenanthrene skeleton is coplanar. The overall crystal packing revealed that it has reverse staggered parallel and stratified arrangement. And a one-dimensional interaction model was formed by two kinds of pi-pi interactions between the two adjacent molecules at upper and lower levels. The decomposition mechanism of compound 3 is complex.

引用

页码：908 / 912

页数：5

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