Results of a Round-Robin with di-tertiary-butyl peroxide in various adiabatic equipment for assessment of runaway reaction hazards

被引：39

作者：

Kersten, RJA

Boers, MN

Stork, MM

Visser, C

机构：

[1] TNO, Def Secur & Safety, NL-2280 AA Rijswijk, Netherlands

[2] DSM Technopartners, Geleen, Netherlands

[3] Shell Int Chem, Amsterdam, Netherlands

来源：

JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES | 2005年 / 18卷 / 03期

关键词：

adiabatic calorimetry; reaction kinetics; runaway reaction; peroxides;

D O I：

10.1016/j.jlp.2005.03.003

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The results of a Round-Robin test on the decomposition reaction of 15% w/w di-tertiary-butyl peroxide (DTBP) in toluene are described in the present paper. The aim of the Round-Robin test was to compare the results of different (pseudo-)adiabatic reaction calorimeters in terms of accuracy and reliability for practical applications. The experiments were performed in the Accelerating Rate Calorimeter (ARC), Phi-Tec, Pressure Dewar calorimeter (Dewar), temperature controlled reactor (CRVM) and the Automatic Pressure Track Accelerating Calorimeter (APTAC). Although the various types of equipment showed differences in accuracy and reproducibility, in general, no specific type of equipment seems to out-perform the others in the present study. (c) 2005 Published by Elsevier Ltd.

引用

页码：145 / 151

页数：7