Two separable conformers of TATP and analogues exist at room temperature

被引：55

作者：

Denekamp, C ^{[1
]}

Gottlieb, L

Tamiri, T

Tsoglin, A

Shilav, R

Kapon, M

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[2] Rafael Ltd, Dept M4, IL-31021 Haifa, Israel

[3] Israel Police Headquarters, Div Identificat & Forens Sci, IL-91906 Jerusalem, Israel

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 12期

关键词：

D O I：

10.1021/ol050801c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

TATP gives rise to two separable conformations because the barrier for interconversion between them is relatively high at room temperature. This kind of behavior is rare in cyclic organic systems and is the result of poor overlap in the "flip-flop" transition state. The crystal structure of the analogous tricyclohexanone triperoxide also indicates the presence of two conformers.

引用

页码：2461 / 2464

页数：4

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