Di-2-pyridyl ketone oxime in 3d-metal carboxylate cluster chemistry:: a new family of mixed-valence Mn2IIMn2III complexes

被引：38

作者：

Milios, CJ

Raptopoulou, CP

Terzis, A

Vicente, R

Escuer, A ^{[1
]}

Perlepes, SP

机构：

[1] Univ Patras, Dept Chem, Patras 26504, Greece

[2] NCSR Demokritos, Inst Sci Mat, Athens 15310, Greece

[3] Univ Barcelona, Dept Quim Inorgan, Barcelona 08028, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期

关键词：

crystal structures; Di-2-pyridyl ketone oxime; magnetic properties; tetranuclear mixed-valence manganese complexes;

D O I：

10.1016/S1387-7003(03)00183-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several reaction schemes involving di-2-pyridyl ketone oxime, (py)(2)CNOH, Mn sources, RCO2- ligands and X- in MeCN or MeCN/EtOH lead to the new family of mixed-valence complexes [(Mn2Mn2III)-Mn-II(O2CR)(2)X-2{(py)(2)CNO}(2){(py)(2)CO2}(2)] (R = Me, Ph; X = Cl, Br; (py)(2)CO22- = the gem-diolate(-2) form of di-2-pyridyl ketone). The products have been characterized by single crystal X-ray crystallography and exhibit the same structural motif Magnetic studies indicate weak antiferromagnetic exchange interactions in the complexes. (C) 2003 Elsevier Science B.V. All rights reserved.

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页码：1056 / 1060

页数：5

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