Metallic aluminum nanorods: Synthesis via vapor-deposition and applications in al/air batteries

被引:61
作者
Li, Chunsheng [1 ]
Ji, Weiqiang [1 ]
Chen, Jun [1 ]
Tao, Zhanliang [1 ]
机构
[1] Nankai Univ, Inst New Energy Mat Chem, Tianjin 300071, Peoples R China
关键词
ANODIC-DISSOLUTION; NANOWIRES; SYSTEM; GROWTH;
D O I
10.1021/cm7018795
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The fabrication of Al nanorods by a facile vapor-deposition method and their electrochemical performance in Al/air batteries was reported. Aluminum electrodes were prepared by inserting the mixture of active materials Vulcan XC-72 carbon, and poly(tetrafluoroethylene). Al nanoparticles and nanowires have been synthesized by various methods, such as electromigration, electron-beam direct writing lithography, and template processing. Aluminum nanorods were prepared by loading Al powders of 99.99% purity in tungsten boats positioned at middle of a horizontal ceramic tube that was mounted in the center of a conventional tube furnace. The structure developed underwent powder X-ray diffraction, field emission scanning electron microscopy, and transmission electron microscopy. Al/air battery as prepared from Al nanorods displays high discharge specific capacity and average operating voltage, for developing long life battery systems.
引用
收藏
页码:5812 / 5814
页数:3
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