Ruthenium-catalyzed addition of aromatic imines at the ortho C-H bonds to olefins

被引：129

作者：

Kakiuchi, F ^{[1
]}

Yamauchi, M ^{[1
]}

Chatani, N ^{[1
]}

Murai, S ^{[1
]}

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 02期

关键词：

D O I：

10.1246/cl.1996.111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Additions of aromatic imines at the ortho carbon-hydrogen bonds to olefins were catalyzed by ruthenium complexes affording 1:1 addition products in good to excellent yields, In some cases, a by-product arising from dehydrogenative coupling was also obtained, Both aldimines and ketimines reacted well. Olefins such as styrene, 3,3-dimethyl-1-butene, and ethylene yielded corresponding products in good yields.

引用

页码：111 / 112

页数：2

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