Distorted Copper(II) Complex with Unusually Short CF•••Cu Distances

被引：4

作者：

Cody, Claire C. ^{[1
,2
]}

Kelly, H. Ray ^{[1
,2
]}

Mercado, Brandon Q. ^{[1
]}

Batista, Victor S. ^{[1
,2
]}

Crabtree, Robert H. ^{[1
,2
]}

Brudvig, Gary W. ^{[1
,2
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

[2] Yale Univ, Yale Energy Sci Inst, New Haven, CT 06520 USA

来源：

INORGANIC CHEMISTRY | 2021年 / 60卷 / 19期

基金：

美国国家科学基金会;

关键词：

MOLECULAR-ORBITAL METHODS; CARBON-FLUORINE BONDS; GAUSSIAN-BASIS SETS; COORDINATION CHEMISTRY; WATER OXIDATION; INDEX; ATOMS;

D O I：

10.1021/acs.inorgchem.1c01958

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We find a Cu(II)-(L-CF3)(2) complex (L-CF3 = 2,2,2-trifluoro-N-[2-(pyridin-2-yl)propan-2-yl]acetamide) with a distorted "seesaw" geometry. It has the shortest crystallographic CF center dot center dot center dot Cu distances yet reported, to the best of our knowledge (<2.6 A), for which computational and experimental data indicate a secondary bonding interaction. A comparison with a CCl3 version and one without ligand backbone gem-dimethyl groups suggests a steric origin for the distorted geometry, resulting from the specific ligand interactions.

引用

页码：14759 / 14764

页数：6

共 50 条

[1] DISTORTED OCTAHEDRAL COPPER(II) COMPLEX OF CIMETIDINE
SANCHO, A
BORRAS, J
SOTO, L
ESTEBANCALDERON, C
MARTINEZRIPOLL, M
GARCIABLANCO, S
ACTA CRYSTALLOGRAPHICA SECTION A, 1984, 40 : C103 - C103
[2] Synthesis, crystal structure, EPR, and DFT studies of an unusually distorted vanadium(ii) complex
Charles, Philip
Gaspard, Mallory E.
Alvarez, Santiago
Ziegler, Micah S.
Baldansuren, Amgalanbaatar
Armstrong, William H.
Lakshmi, K., V
Bonitatibus, Peter J., Jr.
DALTON TRANSACTIONS, 2022, 51 (32) : 12031 - 12036
[3] Square-planar copper(II) halide complexes of tridentate ligands with π-π stacking interactions and alternating short and long Cu•••Cu distances
Kannappan, R
Tanase, S
Mutikainen, I
Turpeinen, U
Reedijk, J
INORGANICA CHIMICA ACTA, 2005, 358 (02) : 383 - 388
[4] A pentanuclear complex exhibiting two short Ni-Cu distances
Stibrany, RT
Schugar, HJ
Potenza, JA
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M630 - M632
[5] A one-dimensional assembly of a square-planar copper(II) complex with alternating short and long Cu•••Cu distances.: Metal ion spin-exchange via π-π interactions
Das, S
Muthukumaragopal, GP
Pal, S
Pal, S
NEW JOURNAL OF CHEMISTRY, 2003, 27 (07) : 1102 - 1107
[6] MODEL OF AN UNSTABLE SYSTEM WITH A COULOMB INTERACTION DISTORTED AT SHORT DISTANCES
KERBIKOV, BO
SOVIET JOURNAL OF NUCLEAR PHYSICS-USSR, 1983, 38 (05): : 673 - 679
[7] EVIDENCE FOR SHORT Cu(I)-Cu(I) DISTANCES IN COPPER-EXCESS SPINELS FROM EXAFS
Benazeth, S.
Danot, M.
Colombet, P.
Dexpert, H.
Lagarde, P.
JOURNAL DE PHYSIQUE, 1986, 47 (C-8): : 247 - 250
[8] DISTORTED TETRAHEDRAL COPPER(II) COMPLEX OF A TETRADENTATE SCHIFF-BASE LIGAND
ELDER, RC
HILL, MC
INORGANIC CHEMISTRY, 1979, 18 (03) : 729 - 732
[9] Unusually Short Ce-Ru Distances in CeRuAl and Related Compounds
Hermes, Wilfried
Matar, Samir F.
Poettgen, Rainer
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2009, 64 (08): : 901 - 908
[10] In situ reduction of copper(II) forming an unusually air stable linear complex of copper(I) with a fluorescent tag
Banthia, S
Samanta, A
INORGANIC CHEMISTRY, 2004, 43 (22) : 6890 - 6892

← 1 2 3 4 5 →