A chiral stationary phase coated by surface molecularly imprinted polymer for separating 1,1′-binaphthalene-2,2′-diamine enantiomer by high performance liquid chromatography

被引：28
作者：
Dong, Hongxing [1 ]
Zheng, Meixia [1 ]
Ou, Yiling [1 ]
Zhang, Chunhong [1 ]
Liu, Lijia [1 ]
Li, Junqing [1 ]
Yang, Xiaoguang [1 ]
机构：
[1] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Polymer Mat Res Ctr, Key Lab Supertight Mat & Surface Technol,Minist E, Harbin 150001, Peoples R China
来源：
JOURNAL OF CHROMATOGRAPHY A | 2015年 / 1376卷
基金：
中国国家自然科学基金;
关键词：
1,1 '-Binaphthalene-2,2 '-diamine; Coating; Chiral separation; Surface molecularly imprinted polymers; SELECTIVE RECOGNITION; AQUEOUS-SOLUTION; SILICA-GEL; NANOPARTICLES; LIGANDS; DERIVATIVES; MONOMER; CARBON;
D O I：
10.1016/j.chroma.2014.12.009
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
This report describes novel pathway for the development of a new type of CSP. A chiral stationary phase (CSP) prepared by coating a molecularly imprinted polymer (MIP) on the surface of silica gel (SMIP-CSP) showed a high separation factor (3.39) in separating racemic 1,1'-binaphthalene-2,2'-diamine (DABN) by high performance liquid chromatography (HPLC). Being the crosslinking agent, ethylene glycol dimethacrylate (EGDMA) was copolymerized with the monomer, methacrylic acid (MAA), in the presence of (R)-DABN as the template molecules on the surface of the silica gel particles to produce the SMIP-CSPs. The effects of the pretreatment temperature, the (R)-DABN content and the type of silica gel and monomer in the SMIP-CSPs on the separation of the racemic DABN were systematically investigated. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：172 / 176
页数：5
相关论文
共 25 条
[1]   Surface-imprinted chitosan-coated magnetic nanoparticles modified multi-walled carbon nanotubes biosensor for detection of bovine serum albumin [J].
Chen, Hong-Jun ;
Zhang, Zhao-Hui ;
Luo, Li-Juan ;
Yao, Shou-Zhuo .
SENSORS AND ACTUATORS B-CHEMICAL, 2012, 163 (01) :76-83
[2]  
Dong H.X., 2014, ACTA CHROMATOGR, V26, P1
[3]   An ion-imprinted amino-functionalized silica gel sorbent prepared by hydrothermal assisted surface imprinting technique for selective removal of cadmium (II) from aqueous solution [J].
Fan, Hong-Tao ;
Li, Jing ;
Li, Zhan-Chao ;
Sun, Ting .
APPLIED SURFACE SCIENCE, 2012, 258 (08) :3815-3822
[4]   ASYMMETRIC CATALYTIC REDUCTION OF CARBONYL-COMPOUNDS USING C-2 SYMMETRICAL DIAMINES AS CHIRAL LIGANDS [J].
GAMEZ, P ;
FACHE, F ;
LEMAIRE, M .
TETRAHEDRON-ASYMMETRY, 1995, 6 (03) :705-718
[5]   Molecular imprinted material prepared by novel surface imprinting technique for selective adsorption of pirimicarb [J].
Gao, Baojiao ;
Wang, Jian ;
An, Fuqiang ;
Liu, Qing .
POLYMER, 2008, 49 (05) :1230-1238
[6]   Preparation and recognition performance of cholic acid-imprinted material prepared with novel surface-imprinting technique [J].
Gao, Baojiao ;
Lu, Jinhua ;
Chen, Zhiping ;
Guo, Jinfeng .
POLYMER, 2009, 50 (14) :3275-3284
[7]   Smart surface imprinting polymer nanospheres for selective recognition and separation of glycoprotein [J].
Gao, Feng-Xian ;
Ma, Xiao-Tong ;
He, Xi-Wen ;
Li, Wen-You ;
Zhang, Yu-Kui .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2013, 433 :191-199
[8]   Solvent-free asymmetric direct aldol reactions organocatalysed by recoverable (Sa)-binam-L-prolinamide [J].
Guillena, Gabriela ;
del Carmen Hita, Maria ;
Najera, Carmen ;
Viozquez, Santiago F. .
TETRAHEDRON-ASYMMETRY, 2007, 18 (19) :2300-2304
[9]   Synthesis and characterization of new chiral octadentate nitrogen ligands and related copper(II) complexes as catalysts for stereoselective oxidation of catechols [J].
Gullotti, M ;
Santagostini, L ;
Pagliarin, R ;
Granata, A ;
Casella, L .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 235 (1-2) :271-284
[10]   Imprinting of protein over silica nanoparticles via surface graft copolymerization using low monomer concentration [J].
He, Hongyan ;
Fu, Guoqi ;
Wang, Yan ;
Chai, Zhihua ;
Jiang, Yizhe ;
Chen, Zilun .
BIOSENSORS & BIOELECTRONICS, 2010, 26 (02) :760-765
123