Biodiesel production from wild mustard (Sinapis Arvensis) seed oil using a novel heterogeneous catalyst of LaTiO3 nanoparticles

被引:63
作者
Rezania, Shahabaldin [1 ]
Mahdinia, Saeideh [2 ]
Oryani, Bahareh [3 ]
Cho, Jinwoo [1 ]
Kwon, Eilhann E. [1 ]
Bozorgian, Alireza [4 ]
Nodeh, Hamid Rashidi [5 ]
Darajeh, Negisa [6 ]
Mehranzamir, Kamyar [7 ]
机构
[1] Sejong Univ, Dept Environm & Energy, Seoul 05006, South Korea
[2] Bu Ali Sina Univ, Fac Chem, Hamadan, Hamadan, Iran
[3] Seoul Natl Univ, Coll Engn, Technol Management Econ & Policy Program, 1 Gwanak Ro, Seoul 08826, South Korea
[4] Islamic Azad Univ, Dept Chem Engn, Mahshahr Branch, Mahshahr, Iran
[5] Stand Res Inst, Food Technol & Agr Prod Res Ctr, Karaj, Iran
[6] Univ Canterbury, Sch Biol Sci, Christchurch 8140, New Zealand
[7] Univ Nottingham Malaysia, Fac Sci & Engn, Dept Elect & Elect Engn, Jalan Broga, Semenyih 43500, Selangor, Malaysia
关键词
Biodiesel production; Wild mustard seed oil; LaTiO3; nanoparticles; Heterogeneous catalyst; LANTHANUM OXIDE; IONIC LIQUID; TRANSESTERIFICATION; ESTERIFICATION; COMPOSITES;
D O I
10.1016/j.fuel.2021.121759
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This study synthesized a novel heterogeneous catalyst using lanthanum titanium dioxide (LaTiO3) nanoparticles via co-precipitation and calcination processes. The proposed LaTiO3 NPs were used for biodiesel production from wild mustard seed oil in the presence of methanol. The solid catalyst material was characterized by Fouriertransform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and scanning electron microscopy (SEM). The process of trans-esterification was affected by the reaction conditions, such as the molar ratio of alcohol to oil (4:1), amount of catalyst (100 mg), reaction time (60 min), and temperature (80 degrees C). Under optimized conditions, the highest rate of biodiesel was 92.21% at 80 degrees C for 60 min in the presence of LaTiO3 NPs. Finally, the catalyst showed a maintained performance for at least five runs and up to eight runs. This result implied that the reported catalyst has a high potential to produce biodiesel at a reasonable cost and appropriate reaction conditions.
引用
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页数:7
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