PHOTOLUMINESCENCE OF F-CENTERS IN FILMS OF ANODIC ALUMINA

被引:26
作者
Mukhurov, N. I. [1 ]
Zhvavyi, S. P. [1 ]
Gasenkova, I. V. [1 ]
Terekhov, S. N. [1 ]
Pershukevich, P. P. [1 ]
Orlovich, V. A. [1 ]
机构
[1] Natl Acad Sci Belarus, BI Stepanov Phys Inst, Minsk 220072, BELARUS
关键词
anodic alumina; photoluminescence; sulfuric acid; oxygen vacancies; OPTICAL-PROPERTIES; MEMBRANES; FABRICATION;
D O I
10.1007/s10812-010-9367-8
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Results are reported from a study of the optical properties of porous alumina films obtained by anodizing in a water solution of sulfuric acid and modified by thermal annealing in air at T >= 850 degrees C. A comparative analysis of the data shows that the near-UV and visible photoluminescence of alumina anodized in a sulfuric acid solution is caused primarily by oxygen divacancies (F-2, F-2(+), and F-2(2+) centers), while sulfate ions have little effect on the luminescence properties of anodic alumina in this spectral range.
引用
收藏
页码:549 / 555
页数:7
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