Synthesis, characterization and optical properties of hybridized CdS-PVA nanocomposites

Hybrid nanocomposites of US nanoparticles embedded in poly(vinyl alcohol)(PVA) matrixes had been prepared and characterized. The -OH groups acted as the coordination sites for cadmium ion aggregations and nanosized CdS particles were successfully grown in situ at these sites with the release S2- ions from thioacetamide. The density and size of the nanoparticles were found to be a function of molar quantity of cadmium ion used. X-ray diffraction results showed that the obtained US nanoparticles were hexagonal phase. Ionic clustering within the PVA matrix occurred and had provided a confined medium for particles growth in uniform size. The optical properties of the prepared CdS-PVA hybrid nanocomposites were characterized by absorption and emission spectroscopies. The absorption spectra showed a blue shift as compared to bulk CdS band-gap. The photoluminescence studies indicated the emission peak observed in samples could be assigned to the optical transition of the first excitonic state of the CdS nanoparticles. (c) 2007 Elsevier B.V. All rights reserved.