An aurophilicity-determined 3-D bimetallic coordination polymer:: using [Au(CN)2]- to increase structural dimensionality through gold•••gold bonds in (tmeda)Cu[Au(CN)2]2

被引：87

作者：

Leznoff, DB

Xue, BY

Patrick, BO

Sanchez, V

Thompson, RC

机构：

[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada

[2] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Y6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 03期

关键词：

D O I：

10.1039/b007342n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A coordination polymer with the [Au(CN)(2)](-) building block has been prepared and it exhibits weak Au(I)-mediated ferromagnetic interactions; the structure illustrates that aurophilicity is a powerful tool to increase dimensionality, generating a three-dimensional system from a 1-D polymer.

引用

收藏

页码：259 / 260

页数：2

相关论文

共 24 条

[1] PIEZOELECTRIC KCO[AU(CN)2]3 - ROOM-TEMPERATURE CRYSTAL-STRUCTURE OF A COBALT-HARDENED GOLD ELECTRODEPOSITION PROCESS COMPONENT [J].

ABRAHAMS, SC ;

BERNSTEIN, JL ;

LIMINGA, R ;

EISENMANN, ET .

JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (09) :4585-4590

[2] COBALT CYANOAURATE - CRYSTAL-STRUCTURE OF A COMPONENT FROM COBALT-HARDENED GOLD ELECTROPLATING BATHS [J].

ABRAHAMS, SC ;

ZYONTZ, LE ;

BERNSTEIN, JL .

JOURNAL OF CHEMICAL PHYSICS, 1982, 76 (11) :5458-5462

[3] HIGH-TEMPERATURE SERIES EXPANSIONS FOR SPIN-1-2 HEISENBERG MODEL BY METHOD OF IRREDUCIBLE REPRESENTATIONS OF SYMMETRIC GROUP [J].

BAKER, GA ;

RUSHBROOKE, GS ;

GILBERT, HE .

PHYSICAL REVIEW, 1964, 135 (5A) :1272-+

[4] A supramolecular synthon for H-bonded transition metal arrays [J].

Bernhardt, PV .

INORGANIC CHEMISTRY, 1999, 38 (15) :3481-3483

[5] Inorganic crystal engineering using self-assembly of tailored building-blocks [J].

Blake, AJ ;

Champness, NR ;

Hubberstey, P ;

Li, WS ;

Withersby, MA ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138

[6] A new CuI(SCN) structural motif:: synthesis of an uncharged three-dimensional co-ordination network [J].

Blake, AJ ;

Champness, NR ;

Crew, M ;

Hanton, LR ;

Parsons, S ;

Schroder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (10) :1533-1534

[7] THALLIUM DICYANOAURATE(I), TL[AU(CN)2], AND CESIUM DICYANOAURATE(I), CS[AU(CN)2] [J].

BLOM, N ;

LUDI, A ;

BURGI, HB ;

TICHY, K .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (NOV) :1767-1769

[8] Crystal engineering and organometallic architecture [J].

Braga, D ;

Grepioni, F ;

Desiraju, GR .

CHEMICAL REVIEWS, 1998, 98 (04) :1375-1405

[9] The structures of [24-pyrimidinium crown-6] [Au(CN)2]4(NO3)2•2H2O, [24-pyrimidinium crown-6][Au(CN)2]6•5H2O, and [16-pyrimidinium crown-4][Au(CN)2]4•6.5 H2O, in which aurophilic interactions produce trimers, tetramers, and chains of Au(CN)2- ions [J].

Cramer, RE ;

Smith, DW ;

VanDoorne, W .

INORGANIC CHEMISTRY, 1998, 37 (22) :5895-5901

[10]

Dunbar KR, 1997, PROG INORG CHEM, V45, P283