Gas Sensing with High-Resolution Localized Surface Plasmon Resonance Spectroscopy

被引:200
作者
Bingham, Julia M. [1 ]
Anker, Jeffrey N. [1 ]
Kreno, Lauren E. [1 ]
Van Duyne, Richard P. [1 ]
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
基金
美国国家科学基金会;
关键词
ENHANCED RAMAN-SPECTROSCOPY; SILVER NANOPARTICLES; NANOSPHERE LITHOGRAPHY; SENSORS; PHASE; SELECTIVITY; MONOLAYER; SPECTRUM; ARRAY;
D O I
10.1021/ja1074272
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the first inert gas sensing and characterization studies based on high-resolution localized surface plasmon resonance (HR-LSPR) spectroscopy. HR-LSPR was used to detect the extremely small changes (<3 x 10(-4)) in bulk refractive index when the gas was switched between He(g) and Ar(g) or He(g) and N-2(g). We also demonstrate submonolayer sensitivity to adsorbed water from exposure of the sensor to air (40% humidity) versus dry N-2(g). These measurements significantly expand the applications space and characterization tools for plasmonic nanosensors.
引用
收藏
页码:17358 / 17359
页数:2
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