Silyloxy-cope rearrangement of chiral aldol adducts

被引：26
作者：
Black, WC
Giroux, A
Greidanus, G
机构：
[1] Merck Frosst Ctr. for Therapeut. R., Pointe-Claire-Dorval, Que. H9R 4P8
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 26期
关键词：
D O I：
10.1016/0040-4039(96)00904-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The silyloxy-Cope rearrangement of a chiral 1,5-diene generated from aldol condensation proceeds in high yield and selectivity under mild thermal conditions to generate a new stereocenter five atoms removed from the chiral auxiliary. Copyright (C) 1996 Elsevier Science Ltd
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收藏
页码：4471 / 4474
页数：4
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