An infrared and solid-state nmr study of the H2S adsorption on basic zeolite

被引：0

作者：

Gaillard, M ^{[1
]}

Montouillout, V ^{[1
]}

Maugé, F ^{[1
]}

Fernandez, C ^{[1
]}

机构：

[1] ENSICAEN, CNRS, Catalyse & Spectrochim Lab, F-14050 Caen, France

来源：

RECENT ADVANCES IN THE SCIENCE AND TECHNOLOGY OF ZEOLITES AND RELATED MATERIALS, PTS A - C | 2004年 / 154卷

关键词：

H2S; zeolites; SH species; in situ spectroscopy;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The modification of surface properties resulting from H2S adsorption on a fully sodium-exchanged Y zeolite was studied in situ using a combination of infrared and Solid-State NMR spectroscopy. In order to perform in situ measurement in the same conditions with both techniques, a homebuilt device for preparing the NMR samples under vacuum or controlled atmosphere was used. Double-resonance NMR methods were achieved for a complete assignment of the different lines in proton NMR spectra. A small fraction of H2S is shown to adsorb dissociatively on NaY whereas the main part of H2S interacts non-dissociatively, either by coordination with the Na+ cations or by H-bonding.

引用

页码：1679 / 1685

页数：7

共 28 条

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