Photochemical and thermal isomerization of a ruthenium(II)-alloxazine complex involving an unusual coordination mode

被引：38

作者：

Miyazaki, Soushi ^{[1
]}

Kojima, Takahiko ^{[1
]}

Fukuzumi, Shunichi ^{[1
]}

机构：

[1] Osaka Univ, SORST, Japan Sci & Technol Agcy, Grad Sch Engn,Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 05期

关键词：

D O I：

10.1021/ja077954a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Ru(II) complex having a flavin analogue as a ligand in a unusual coordination mode exhibits a photochemical and thermal isomerizations, the bistability of the complex is attained by chelate effect and intramolecular CH center dot center dot center dot O interaction.

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收藏

页码：1556 / +

页数：3

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