Highly Fluorescent Metal-Organic Framework for the Sensing of Volatile Organic Compounds

被引：83

作者：

Jackson, Sam L. ^{[1
]}

Rananaware, Anushri ^{[1
]}

Rix, Colin ^{[1
]}

Bhosale, Sheshanath V. ^{[1
]}

Latham, Kay ^{[1
]}

机构：

[1] RMIT Univ, Sch Appl Sci, GPO Box 2476, Melbourne, Vic 3001, Australia

来源：

CRYSTAL GROWTH & DESIGN | 2016年 / 16卷 / 06期

基金：

澳大利亚研究理事会;

关键词：

AGGREGATION-INDUCED EMISSION; TETRAPHENYLETHYLENE; LUMINOGEN; BEHAVIOR; SENSORS;

D O I：

10.1021/acs.cgd.6b00428

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Communication describes an infinite 1D ribbon metal organic framework (MOF) that crystallizes to produce large channels (13.4 x 17.5 angstrom) and exhibits strong aggregation enhanced fluorescence emission. The network is composed, of tetrapyridine tetraphenylethene molecules coordinating to ZnCl2 nodes. When activated; the network exhibits enhanced turn-on fluorescence in response to methyl-substituted volatile organic compounds (VOCs) and quenching in response to nitro-substituted VOCs. This MOF shows potential as a valuable sensor due to its high surface area, highly fluorescent TPE moiety, and significant response to VOCs.

引用

页码：3067 / 3071

页数：5

共 28 条

[1] Recent advances in nanomaterial-based sensors for detection of trace nitroaromatic explosives [J].

Akhgari, Farhad ;

Fattahi, Hassan ;

Oskoei, Yones Mosaei .

SENSORS AND ACTUATORS B-CHEMICAL, 2015, 221 :867-878

[2] Right handed chiral superstructures from achiral molecules: self-assembly with a twist [J].

Anuradha ;

Duong Duc La ;

Al Kobaisi, Mohammad ;

Bhosale, Sheshanath V. .

SCIENTIFIC REPORTS, 2015, 5

[3] Research Update: Mesoporous sensor nanoarchitectonics [J].

Ariga, Katsuhiko ;

Yamauchi, Yusuke ;

Ji, Qingmin ;

Yonamine, Yusuke ;

Hill, Jonathan P. .

APL MATERIALS, 2014, 2 (03)

[4] A Luminescent Metal-Organic Framework with Lewis Basic Pyridyl Sites for the Sensing of Metal Ions [J].

Chen, Banglin ;

Wang, Liangbo ;

Xiao, Yunqing ;

Fronczek, Frank R. ;

Xue, Ming ;

Cui, Yuanjing ;

Qian, Guodong .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (03) :500-503

[5] Dual-Modal MRI Contrast Agent with Aggregation-Induced Emission Characteristic for Liver Specific Imaging with Long Circulation Lifetime [J].

Chen, Yilong ;

Li, Min ;

Hong, Yuning ;

Lam, Jacky W. Y. ;

Zheng, Qichang ;

Tang, Ben Zhong .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (13) :10783-10791

[6] Unusual Adsorption Behavior on Metal-Organic Frameworks [J].

Fairen-Jimenez, David ;

Seaton, Nigel A. ;

Duren, Tina .

LANGMUIR, 2010, 26 (18) :14694-14699

[7]

Hurd JA, 2009, NAT CHEM, V1, P705, DOI [10.1038/NCHEM.402, 10.1038/nchem.402]

[8] Clathrate directed assembly of tetrapyridyl-tetraphenylethylene metal-organic frameworks [J].

Jackson, Sam L. ;

Rananaware, Anushri ;

Rix, Colin ;

Bhosale, Sheshanath V. ;

Latham, Kay .

RSC ADVANCES, 2015, 5 (102) :84134-84141

[9] Metal-Organic Framework Materials as Chemical Sensors [J].

Kreno, Lauren E. ;

Leong, Kirsty ;

Farha, Omar K. ;

Allendorf, Mark ;

Van Duyne, Richard P. ;

Hupp, Joseph T. .

CHEMICAL REVIEWS, 2012, 112 (02) :1105-1125

[10] Metal-organic framework materials as catalysts [J].

Lee, JeongYong ;

Farha, Omar K. ;

Roberts, John ;

Scheidt, Karl A. ;

Nguyen, SonBinh T. ;

Hupp, Joseph T. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1450-1459

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