The synthesis by successive ionic layer deposition of SnMo0.6Oy•nH2O nanolayers on silica

被引：17

作者：

Gulina, LB ^{[1
]}

Tolstoy, VP ^{[1
]}

机构：

[1] St Petersburg State Univ, Dept Chem, St Petersburg 198504, Russia

来源：

THIN SOLID FILMS | 2003年 / 440卷 / 1-2期

基金：

俄罗斯基础研究基金会;

关键词：

tin oxide; molybdenum oxide; deposition process; X-ray photoelectron spectroscopy;

D O I：

10.1016/S0040-6090(03)00684-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The conditions for the layer-by-layer synthesis by the method of the successive ionic layer deposition of Sn(IV)Mo(VI,V)(0.6)Oy(.)nH(2)O nanolayers on a silica surface were determined for the first time. The nanolayer thickness was controlled by the number of successive cycles. The composition and structure of these films were determined using Fourier transform infrared and UV/Vis transmission spectroscopy, X-ray photoelectron spectroscopy, X-ray difraction, and electron microprobe. It was found that under heating up to 200 degreesC, molecular water and hydroxyl groups are removed from the nanolayers, the bonds Mo-O-Mo and Sn-O-Mo are formed, and Mo(V) is oxidized to Mo(VI). (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：74 / 77

页数：4

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